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	Spin-canting in a 1d chain mn(ii) complex with alternating double end-on and double end-to-end azido bridging ligands
	Zhang, Jian-Ying; Liu, Cai-Ming; Zhang, De-Qing; Gao, Song; Zhu, Dao-Ben
刊名	Inorganic chemistry communications
	2007-08-01
卷号	10期号:8页码:897-901
关键词	Manganese(ii) complex Azido ligand Coordination polymer Spin canting Magnetic property Crystal structure
ISSN号	1387-7003
DOI	10.1016/j.inoche.2007.04.004
通讯作者	Liu, cai-ming(cmliu@iccas.ac.cn)
英文摘要	A new one-dimensional (ii)) azido-bridged manganese(ii) complex, [mn(dpq)(n-3)2](n) [dpq = dipyrido-(3,2-d:2',3'-f)-quinoxaline] (1), was synthesized and characterized. crystal structure study reveals that 1 contains a id manganese(ii) chain bridged by alternating double end-to-end (ee) and double end-on (eo) azido ligands. the strong interchain pi-pi stacking interaction extends the structure into a 2d supramolecular array. the analysis of magnetic data indicates that the eo- and ee-azido bridges mediate the ferromagnetic and antiferromagnetic interactions, respectively. interestingly, complex 1 exhibits a weak ferromagnetic property below 6 k probably due to spin canting. (c) 2007 elsevier b.v. all rights reserved.
WOS关键词	FERROMAGNETIC-ANTIFERROMAGNETIC INTERACTIONS ; MANGANESE(II) COORDINATION POLYMERS ; MONTE-CARLO-SIMULATION ; MAGNETIC-PROPERTIES ; CRYSTAL-STRUCTURE ; STRUCTURAL-CHARACTERIZATION ; WEAK FERROMAGNETISM ; MAGNETOSTRUCTURAL CORRELATIONS ; SPONTANEOUS RESOLUTION ; MOLECULAR MATERIAL
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000248769700013
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2383167
专题	中国科学院大学
通讯作者	Liu, Cai-Ming
作者单位	1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat & Applicat, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,et al. Spin-canting in a 1d chain mn(ii) complex with alternating double end-on and double end-to-end azido bridging ligands[J]. Inorganic chemistry communications,2007,10(8):897-901.
APA	Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,Gao, Song,&Zhu, Dao-Ben.(2007).Spin-canting in a 1d chain mn(ii) complex with alternating double end-on and double end-to-end azido bridging ligands.Inorganic chemistry communications,10(8),897-901.
MLA	Zhang, Jian-Ying,et al."Spin-canting in a 1d chain mn(ii) complex with alternating double end-on and double end-to-end azido bridging ligands".Inorganic chemistry communications 10.8(2007):897-901.

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