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Quasi-solid state dye-sensitized solar cells based on pyridine or imidazole containing copolymer chemically crosslinked gel electrolytes
Li MinYu; Feng ShuJing; Fang ShiBi; Xiao XuRui; Li XuePing; Zhou XiaoWen; Lin Yuan
刊名Chinese science bulletin
2007-09-01
卷号52期号:17页码:2320-2325
关键词Dye-sensitized solar cells Polymer electrolytes Polymer chemically crosslinking Energy conversion efficiency
ISSN号1001-6538
DOI10.1007/s11434-007-0340-8
通讯作者Zhou xiaowen(a1703@iccas.ac.cn)
英文摘要Quasi-solid state dye-sensitized solar cells based on chemically crosslinking with backbone polymers of poly(vinylpyridine-co-acrylonitrile) (p(vp-co-an)) or poly(vinylimidazole-co-acrylonitrile) (p(vim-co-an)) and diiodide compounds of i(ch2)(6)i or i(ch2ch2o)(n)ch2ch2i solidified ec/pc/ki/i-2 gel electrolytes have been fabricated. the ionic conductivities and apparent diffusion coefficients of i-3(-) of the electrolytes and cell performances have been investigated. providing chemically crosslinking points, pyridine or imidazole from the backbone polymers benefited the open circuit voltage and fill factor of the cells. consequently, the overall energy conversion efficiencies of the quasi-solid dsscs improved over 10% even near 20% from that of the liquid electrolyte before solidification. besides, the employing of crosslinker i(ch2ch2o)(n)ch2ch2i showed higher electrolytic and cell characters than that of i(ch2)(6)i.
WOS关键词POLYMER ELECTROLYTE ; ADDITIVES ; PERFORMANCE ; CONVERSION
WOS研究方向Science & Technology - Other Topics
WOS类目Multidisciplinary Sciences
语种英语
出版者SCIENCE CHINA PRESS
WOS记录号WOS:000249381100004
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2382643
专题中国科学院大学
通讯作者Zhou XiaoWen
作者单位1.Chinese Acad Sci, Inst Chem, Key Lab PhotoChem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Li MinYu,Feng ShuJing,Fang ShiBi,et al. Quasi-solid state dye-sensitized solar cells based on pyridine or imidazole containing copolymer chemically crosslinked gel electrolytes[J]. Chinese science bulletin,2007,52(17):2320-2325.
APA Li MinYu.,Feng ShuJing.,Fang ShiBi.,Xiao XuRui.,Li XuePing.,...&Lin Yuan.(2007).Quasi-solid state dye-sensitized solar cells based on pyridine or imidazole containing copolymer chemically crosslinked gel electrolytes.Chinese science bulletin,52(17),2320-2325.
MLA Li MinYu,et al."Quasi-solid state dye-sensitized solar cells based on pyridine or imidazole containing copolymer chemically crosslinked gel electrolytes".Chinese science bulletin 52.17(2007):2320-2325.
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