In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane | |
Ji Baofen1,2; Wang Jibo1; Chu Wenling1; Zhu Xuefeng1; Yang Weishen1; Lin Liwu1 | |
刊名 | chinese journal of catalysis |
2009-05-01 | |
卷号 | 30期号:5页码:375-377 |
关键词 | propane propene vanadium and magnesium oxide catalyst oxygen activity solid electrolyte potentiometry |
通讯作者 | 杨维慎 |
产权排序 | 1;1 |
英文摘要 | periodic oscillations in the oxygen activity on a mg2v2o7 catalyst during the oxidative dehydrogenation of propane were monitored in situ by solid electrolyte potentiometry. the results directly showed that the catalyst was first reduced and then oxidized. the rate-determining step was the adsorption and activation of propane on the mg2v2o7 catalyst. propane and oxygen were adsorbed on different sites of the mg2v2o7 catalyst. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | mg-o catalysts ; selective oxidation ; propylene ; molybdate ; kinetics ; acid |
收录类别 | SCI |
原文出处 | false |
语种 | 英语 |
WOS记录号 | WOS:000266790700001 |
公开日期 | 2010-11-30 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/101821] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ji Baofen,Wang Jibo,Chu Wenling,et al. In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane[J]. chinese journal of catalysis,2009,30(5):375-377. |
APA | Ji Baofen,Wang Jibo,Chu Wenling,Zhu Xuefeng,Yang Weishen,&Lin Liwu.(2009).In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane.chinese journal of catalysis,30(5),375-377. |
MLA | Ji Baofen,et al."In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane".chinese journal of catalysis 30.5(2009):375-377. |
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