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High ionic conductivity of all-solid polymer electrolytes based on polyorganophosphazenes
Zhou, Shuhua; Fang, Shibi
刊名European polymer journal
2007-08-01
卷号43期号:8页码:3695-3700
关键词Solid polymer electrolyte Ionic conductivity Polyorganophosphazene Cross-linkable
ISSN号0014-3057
DOI10.1016/j.eurpolymj.2007.06.001
通讯作者Fang, shibi(fangsb@iccas.ac.cn)
英文摘要A series of all-solid polymer electrolytes were prepared by cross-linking new designed poly(organophosphazene) macromonomers. the ionic conductivities of these all-solid, dimensional steady polymer electrolytes were reported. the temperature dependence of ionic conductivity of the all-solid polymer electrolytes suggested that the ionic transport is correlated with the segmental motion of the polymer. the relationship between lithium salts content and ionic conductivity was discussed and investigated by infrared spectrum. furthermore, the polarity of the host materials was thought to be a key to the ionic conductivity of polymer electrolyte. the all-solid polymer electrolytes based on these poly(organophosphazenes) showed ionic conductivity of 10(-4) s cm(-1) at room temperature. (c) 2007 elsevier ltd. all rights reserved.
WOS关键词NETWORK POLYMER ; POLY(ETHYLENE OXIDE) ; SIDE-GROUPS ; POLYPHOSPHAZENES ; SYSTEMS
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000249446700063
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2381527
专题中国科学院大学
通讯作者Fang, Shibi
作者单位1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Zhou, Shuhua,Fang, Shibi. High ionic conductivity of all-solid polymer electrolytes based on polyorganophosphazenes[J]. European polymer journal,2007,43(8):3695-3700.
APA Zhou, Shuhua,&Fang, Shibi.(2007).High ionic conductivity of all-solid polymer electrolytes based on polyorganophosphazenes.European polymer journal,43(8),3695-3700.
MLA Zhou, Shuhua,et al."High ionic conductivity of all-solid polymer electrolytes based on polyorganophosphazenes".European polymer journal 43.8(2007):3695-3700.
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