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	Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. a novel tetrameric cluster of [{(fefe12iii)-fe-ii(mu(3)-oh)(12)(mu(4)-po4)(4)}(b-alpha-pw9o34)(4)](22-)
	Zhao, Jun-Wei; Zhang, Jie; Zheng, Shou-Tian; Yang, Guo-Yu
刊名	Inorganic chemistry
	2007-12-24
卷号	46期号:26页码:10944-10946
ISSN号	0020-1669
通讯作者	Yang, guo-yu(ygy@fjirsm.ac.cn)
英文摘要	A novel tetrameric cluster, (en h-2)(3.5)h-15[{(fefeiii)-fe-ii](12)(mu(3)-oh)(12)(mu(4)-po4)(4)}(b-alpha-pw9o34)(4)]center dot 83h(2)o (1; en = ethylenediamine), has been hydrothermally synthesized and characterized by ir, optical diffuse reflectance, thermogravimetric analysis, and single-crystal x-ray diffraction. the skeleton of 1 is composed of four tri-fe-iii-substituted [fe-3(iii)(mu(3)-oh)(3)(b-alpha-pw9o34)](3-) keggin moieties fused together through a (fe2o2)-o-ii unit and four mu(4)-po4 bridges, resulting in a unique tetramer with c-2 symmetry. magnetic measurements indicate that 1 reveals the antiferromagnetic interactions between fe-ii and fe-iii centers.
WOS关键词	MAGNETIC-PROPERTIES ; CRYSTAL-STRUCTURE ; COMPLEXES ; POLYOXOTUNGSTATE ; HETEROPOLYANIONS ; TUNGSTOPHOSPHATE ; POLYOXOANIONS ; COORDINATION ; ANIONS ; WHEEL
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000251773700003
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2381459
专题	中国科学院大学
通讯作者	Yang, Guo-Yu
作者单位	Chinese Acad Sci, Fujian Inst Res Struct Matter, Grad Sch, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Jun-Wei,Zhang, Jie,Zheng, Shou-Tian,et al. Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. a novel tetrameric cluster of [{(fefe12iii)-fe-ii(mu(3)-oh)(12)(mu(4)-po4)(4)}(b-alpha-pw9o34)(4)](22-)[J]. Inorganic chemistry,2007,46(26):10944-10946.
APA	Zhao, Jun-Wei,Zhang, Jie,Zheng, Shou-Tian,&Yang, Guo-Yu.(2007).Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. a novel tetrameric cluster of [{(fefe12iii)-fe-ii(mu(3)-oh)(12)(mu(4)-po4)(4)}(b-alpha-pw9o34)(4)](22-).Inorganic chemistry,46(26),10944-10946.
MLA	Zhao, Jun-Wei,et al."Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. a novel tetrameric cluster of [{(fefe12iii)-fe-ii(mu(3)-oh)(12)(mu(4)-po4)(4)}(b-alpha-pw9o34)(4)](22-)".Inorganic chemistry 46.26(2007):10944-10946.

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