Novel gaseous transient species: generation and characterization | |
Zeng XiaoQing; Wang DianXun | |
刊名 | Science in china series b-chemistry |
2007-04-01 | |
卷号 | 50期号:2页码:145-169 |
关键词 | Reactive halogen species Radicals Pseudohalogen compounds Hel photoelectron spectroscopy (pes) Quantum chemical calculations |
ISSN号 | 1006-9291 |
DOI | 10.1007/s11426-007-0020-1 |
通讯作者 | Wang dianxun(wangdx@iccas.ac.cn) |
英文摘要 | Due to special properties of transient species, such as short-lived, unstable, reactive, and even explosive, the generation and subsequent characterization is a great challenge for experimental chemists. in our laboratory, systematic researches have been carried out to investigate novel transient species: reactive halogen species (rhs), short-lived free radicals, and metastable pseudohalogen compounds, based on the successive technical improvements on the hel photoelectron spectroscopy (pes). in this review, the topic mainly focuses on innovative methods of generating novel transient species, and subsequent geometric and electronic structure characterizations of these species combined with quantum chemical calculations. |
WOS关键词 | DIFFERENT IONIC STATES ; HEI PHOTOELECTRON-SPECTRUM ; 1ST EXPERIMENTAL-OBSERVATION ; GAS-PHASE GENERATION ; FREE-RADICAL NO3 ; ELECTRONIC-STRUCTURE ; IONIZATION ENERGIES ; BROMINE NITRATE ; AB-INITIO ; STRATOSPHERIC CHLORINE |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
出版者 | SCIENCE CHINA PRESS |
WOS记录号 | WOS:000247154900001 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2380939 |
专题 | 中国科学院大学 |
通讯作者 | Wang DianXun |
作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Zeng XiaoQing,Wang DianXun. Novel gaseous transient species: generation and characterization[J]. Science in china series b-chemistry,2007,50(2):145-169. |
APA | Zeng XiaoQing,&Wang DianXun.(2007).Novel gaseous transient species: generation and characterization.Science in china series b-chemistry,50(2),145-169. |
MLA | Zeng XiaoQing,et al."Novel gaseous transient species: generation and characterization".Science in china series b-chemistry 50.2(2007):145-169. |
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