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Novel gaseous transient species: generation and characterization
Zeng XiaoQing; Wang DianXun
刊名Science in china series b-chemistry
2007-04-01
卷号50期号:2页码:145-169
关键词Reactive halogen species Radicals Pseudohalogen compounds Hel photoelectron spectroscopy (pes) Quantum chemical calculations
ISSN号1006-9291
DOI10.1007/s11426-007-0020-1
通讯作者Wang dianxun(wangdx@iccas.ac.cn)
英文摘要Due to special properties of transient species, such as short-lived, unstable, reactive, and even explosive, the generation and subsequent characterization is a great challenge for experimental chemists. in our laboratory, systematic researches have been carried out to investigate novel transient species: reactive halogen species (rhs), short-lived free radicals, and metastable pseudohalogen compounds, based on the successive technical improvements on the hel photoelectron spectroscopy (pes). in this review, the topic mainly focuses on innovative methods of generating novel transient species, and subsequent geometric and electronic structure characterizations of these species combined with quantum chemical calculations.
WOS关键词DIFFERENT IONIC STATES ; HEI PHOTOELECTRON-SPECTRUM ; 1ST EXPERIMENTAL-OBSERVATION ; GAS-PHASE GENERATION ; FREE-RADICAL NO3 ; ELECTRONIC-STRUCTURE ; IONIZATION ENERGIES ; BROMINE NITRATE ; AB-INITIO ; STRATOSPHERIC CHLORINE
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者SCIENCE CHINA PRESS
WOS记录号WOS:000247154900001
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2380939
专题中国科学院大学
通讯作者Wang DianXun
作者单位1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
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Zeng XiaoQing,Wang DianXun. Novel gaseous transient species: generation and characterization[J]. Science in china series b-chemistry,2007,50(2):145-169.
APA Zeng XiaoQing,&Wang DianXun.(2007).Novel gaseous transient species: generation and characterization.Science in china series b-chemistry,50(2),145-169.
MLA Zeng XiaoQing,et al."Novel gaseous transient species: generation and characterization".Science in china series b-chemistry 50.2(2007):145-169.
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