Highly diastereoselective reactions of 2-lithiated indoles with chiral n-tert-butanesulfinyl aldimines for the synthesis of chiral (2-indolyl) methanamine derivatives | |
Cheng, Liang; Liu, Li; Sui, Yong; Wang, Dong; Chen, Yong-Jun | |
刊名 | Tetrahedron-asymmetry
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2007-08-09 | |
卷号 | 18期号:15页码:1833-1843 |
ISSN号 | 0957-4166 |
DOI | 10.1016/j.tetasy.2007.07.029 |
通讯作者 | Liu, li(lliu@mail.iccas.ac.cn) |
英文摘要 | Nucleophilic addition reactions of 2-lithiated n-phenylsulfonylindoles with (r)-n-tert-butanesulfinyl aldimines provided chiral (2-indolyl) methanamine derivatives in moderate to good yields (up to 100%) with excellent diastereoselectivities (>99: 1), in which no additional lewis acids were required. (c) 2007 elsevier ltd. all rights reserved. |
WOS关键词 | FRIEDEL-CRAFTS REACTION ; ASYMMETRIC-SYNTHESIS ; SULFINYL IMINES ; ORGANOMETALLIC REAGENTS ; GENERAL-METHOD ; AMINO-ACIDS ; SULFINIMINES ; TRANSFORMATIONS ; 1,2-ADDITIONS ; INDUCTION |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000250063000013 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2380808 |
专题 | 中国科学院大学 |
通讯作者 | Liu, Li |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Biol Chem Lab, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Cheng, Liang,Liu, Li,Sui, Yong,et al. Highly diastereoselective reactions of 2-lithiated indoles with chiral n-tert-butanesulfinyl aldimines for the synthesis of chiral (2-indolyl) methanamine derivatives[J]. Tetrahedron-asymmetry,2007,18(15):1833-1843. |
APA | Cheng, Liang,Liu, Li,Sui, Yong,Wang, Dong,&Chen, Yong-Jun.(2007).Highly diastereoselective reactions of 2-lithiated indoles with chiral n-tert-butanesulfinyl aldimines for the synthesis of chiral (2-indolyl) methanamine derivatives.Tetrahedron-asymmetry,18(15),1833-1843. |
MLA | Cheng, Liang,et al."Highly diastereoselective reactions of 2-lithiated indoles with chiral n-tert-butanesulfinyl aldimines for the synthesis of chiral (2-indolyl) methanamine derivatives".Tetrahedron-asymmetry 18.15(2007):1833-1843. |
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