Synthesis and thermoelectric properties of p-type sr0.5co4-xfexsb12 skutterudite | |
Zhao Xueying; Chen Lidong; Bai Shengqiang; Pei Yanzhong; Li Xiaoya | |
刊名 | Rare metal materials and engineering |
2007-08-01 | |
卷号 | 36页码:415-418 |
关键词 | Fe doping Filled skutterudite Thermoelectric |
ISSN号 | 1002-185X |
通讯作者 | Zhao xueying(zhaoxy@mail.sic.ac.cn) |
英文摘要 | Skutterudite compounds sr0.5co4-xfexsb12 were synthesized by melting method and the thermal and electrical properties were measured in the temperature range of 300 similar to 850 k. the results of x-ray diffraction (xrd) and electron microprobe analyses (epma) identified that all the samples contain sr0.5co4-xfexsb12 skutterudite as the main phase with a trace amount of fesb2 and cosb2 impurities. all samples exhibit p-type conduction. the carrier concentration and electrical conductivity of the samples increase with increasing iron content and the seebeck coefficient decreases. the lattice thermal conductivity of the samples decreased with the increase of iron content due to the vacancy point defect phonon scattering at co site introduced by iron. the lowest lattice thermal conductivity at room temperature is about 1.97 wrn(-1)k(-2). the highest zt value of 0.6 is obtained for sr0.52co2.32fe1.68sb12 compound at 850 k. |
WOS关键词 | TRANSPORT-PROPERTIES ; FILLING FRACTION ; FE CONTENT ; BARIUM |
WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
WOS类目 | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
出版者 | NORTHWEST INST NONFERROUS METAL RESEARCH |
WOS记录号 | WOS:000250915200121 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2380412 |
专题 | 中国科学院大学 |
通讯作者 | Zhao Xueying |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao Xueying,Chen Lidong,Bai Shengqiang,et al. Synthesis and thermoelectric properties of p-type sr0.5co4-xfexsb12 skutterudite[J]. Rare metal materials and engineering,2007,36:415-418. |
APA | Zhao Xueying,Chen Lidong,Bai Shengqiang,Pei Yanzhong,&Li Xiaoya.(2007).Synthesis and thermoelectric properties of p-type sr0.5co4-xfexsb12 skutterudite.Rare metal materials and engineering,36,415-418. |
MLA | Zhao Xueying,et al."Synthesis and thermoelectric properties of p-type sr0.5co4-xfexsb12 skutterudite".Rare metal materials and engineering 36(2007):415-418. |
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