Rapid preparation of molecularly imprinted capillary monolithic columns by microwave polymerization | |
Zhang Yu-Ping; Zuo Guo-Qiang; Xu Guang-Ri; Li Quan-Min; Yuan Zhuo-Bin | |
刊名 | Chemical journal of chinese universities-chinese |
2007-09-01 | |
卷号 | 28期号:9页码:1654-1656 |
关键词 | Microwave Molecularly imprinted polymer Monolithic column Electrochromatography |
ISSN号 | 0251-0790 |
通讯作者 | Zhang yu-ping(beijing2008zyp@163.com) |
英文摘要 | Microwave irradiation was firstly attempted to prepare molecularly imprinted polymers ( mips monoliths, which were in situ prepared rapidly with methacrylic acid (maa) as a functional monomer, ethylene glycol dimethacrylate (edma) as a cross-linking agent, toluene and isooctane as the porogenic solvents and aibn as an initiator. the baseline separation of isomers of hydroxybenzoic acid was achieved on these monolithic columns with 4-hba as the template, but not on the blank polymer. furthermore, some neutral compounds could also be baseline-separated on the imprinted polymer columns in the modes of pressure-driven capillary electrochromatography and low-pressure driven capillary electrochromatography. it was shown that the monoliths were not only used as the molecularly imprinted polymers but also as the reverse phase chromatographic material. |
WOS关键词 | P-HYDROXYBENZOIC ACID ; ELECTROCHROMATOGRAPHY ; TEMPLATES ; SEPARATION |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
出版者 | HIGHER EDUCATION PRESS |
WOS记录号 | WOS:000249629600012 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2380315 |
专题 | 中国科学院大学 |
通讯作者 | Zhang Yu-Ping |
作者单位 | 1.Henan Inst Sci & Technol, Inst Appl Chem, Xinxiang 453003, Peoples R China 2.Henan Normal Univ, Dept Chem, Xinxiang 453007, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang Yu-Ping,Zuo Guo-Qiang,Xu Guang-Ri,et al. Rapid preparation of molecularly imprinted capillary monolithic columns by microwave polymerization[J]. Chemical journal of chinese universities-chinese,2007,28(9):1654-1656. |
APA | Zhang Yu-Ping,Zuo Guo-Qiang,Xu Guang-Ri,Li Quan-Min,&Yuan Zhuo-Bin.(2007).Rapid preparation of molecularly imprinted capillary monolithic columns by microwave polymerization.Chemical journal of chinese universities-chinese,28(9),1654-1656. |
MLA | Zhang Yu-Ping,et al."Rapid preparation of molecularly imprinted capillary monolithic columns by microwave polymerization".Chemical journal of chinese universities-chinese 28.9(2007):1654-1656. |
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