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Rapid preparation of molecularly imprinted capillary monolithic columns by microwave polymerization
Zhang Yu-Ping; Zuo Guo-Qiang; Xu Guang-Ri; Li Quan-Min; Yuan Zhuo-Bin
刊名Chemical journal of chinese universities-chinese
2007-09-01
卷号28期号:9页码:1654-1656
关键词Microwave Molecularly imprinted polymer Monolithic column Electrochromatography
ISSN号0251-0790
通讯作者Zhang yu-ping(beijing2008zyp@163.com)
英文摘要Microwave irradiation was firstly attempted to prepare molecularly imprinted polymers ( mips monoliths, which were in situ prepared rapidly with methacrylic acid (maa) as a functional monomer, ethylene glycol dimethacrylate (edma) as a cross-linking agent, toluene and isooctane as the porogenic solvents and aibn as an initiator. the baseline separation of isomers of hydroxybenzoic acid was achieved on these monolithic columns with 4-hba as the template, but not on the blank polymer. furthermore, some neutral compounds could also be baseline-separated on the imprinted polymer columns in the modes of pressure-driven capillary electrochromatography and low-pressure driven capillary electrochromatography. it was shown that the monoliths were not only used as the molecularly imprinted polymers but also as the reverse phase chromatographic material.
WOS关键词P-HYDROXYBENZOIC ACID ; ELECTROCHROMATOGRAPHY ; TEMPLATES ; SEPARATION
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者HIGHER EDUCATION PRESS
WOS记录号WOS:000249629600012
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2380315
专题中国科学院大学
通讯作者Zhang Yu-Ping
作者单位1.Henan Inst Sci & Technol, Inst Appl Chem, Xinxiang 453003, Peoples R China
2.Henan Normal Univ, Dept Chem, Xinxiang 453007, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Zhang Yu-Ping,Zuo Guo-Qiang,Xu Guang-Ri,et al. Rapid preparation of molecularly imprinted capillary monolithic columns by microwave polymerization[J]. Chemical journal of chinese universities-chinese,2007,28(9):1654-1656.
APA Zhang Yu-Ping,Zuo Guo-Qiang,Xu Guang-Ri,Li Quan-Min,&Yuan Zhuo-Bin.(2007).Rapid preparation of molecularly imprinted capillary monolithic columns by microwave polymerization.Chemical journal of chinese universities-chinese,28(9),1654-1656.
MLA Zhang Yu-Ping,et al."Rapid preparation of molecularly imprinted capillary monolithic columns by microwave polymerization".Chemical journal of chinese universities-chinese 28.9(2007):1654-1656.
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