Investigation of peo-imidazole ionic liquid oligomer electrolytes for dye-sensitized solar cells | |
Wang, Miao; Xiao, Xurui; Zhou, Xiaowen; Li, Xueping; Lin, Yuan | |
刊名 | Solar energy materials and solar cells
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2007-05-23 | |
卷号 | 91期号:9页码:785-790 |
关键词 | Ionic liquid Oligomer electrolyte Dye-sensitized solar cells Ionic conductivity Conversion efficiency |
ISSN号 | 0927-0248 |
DOI | 10.1016/j.solmat.2007.01.009 |
通讯作者 | Lin, yuan(linyuan@iccas.ac.cn) |
英文摘要 | Ionic liquid oligomers prepared by incorporating imidazolium ionic liquid with peo oligomers were investigated as electrolytes for dye-sensitized solar cells (dsscs). the influences of peo molecular weight and imidazolium group of the ionic liquid oligomers on the ionic conductivity, apparent diffusion coefficient of the redox species in the electrolytes and the performance of solar cells were examined. the structural effects of the ionic liquid oligomers on the kinetic behaviors of dye regeneration and triiodide reduction reactions taken place at nanocrystalline tio2 electrode and pt counter-electrode, respectively, were further studied by cyclic-voltammetry and electrochemical impedance spectroscopy measurements. the increase of the peo molecular weight of the ionic liquid oligomers results in the faster dye regeneration rate and lower charge transfer resistance of triiodide reduction leading to the improvement of cell performance effectively. (c) 2007 elsevier b.v. all rights reserved. |
WOS关键词 | TEMPERATURE MOLTEN-SALTS ; POLYMER ELECTROLYTES ; PHOTOELECTROCHEMICAL CELLS ; CONVERSION EFFICIENCIES ; SILICA NANOPARTICLES ; GEL ELECTROLYTE ; PERFORMANCE ; LIGHT ; BRUSH |
WOS研究方向 | Energy & Fuels ; Materials Science ; Physics |
WOS类目 | Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000246438500006 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2380028 |
专题 | 中国科学院大学 |
通讯作者 | Lin, Yuan |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Miao,Xiao, Xurui,Zhou, Xiaowen,et al. Investigation of peo-imidazole ionic liquid oligomer electrolytes for dye-sensitized solar cells[J]. Solar energy materials and solar cells,2007,91(9):785-790. |
APA | Wang, Miao,Xiao, Xurui,Zhou, Xiaowen,Li, Xueping,&Lin, Yuan.(2007).Investigation of peo-imidazole ionic liquid oligomer electrolytes for dye-sensitized solar cells.Solar energy materials and solar cells,91(9),785-790. |
MLA | Wang, Miao,et al."Investigation of peo-imidazole ionic liquid oligomer electrolytes for dye-sensitized solar cells".Solar energy materials and solar cells 91.9(2007):785-790. |
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