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Investigation of peo-imidazole ionic liquid oligomer electrolytes for dye-sensitized solar cells
Wang, Miao; Xiao, Xurui; Zhou, Xiaowen; Li, Xueping; Lin, Yuan
刊名Solar energy materials and solar cells
2007-05-23
卷号91期号:9页码:785-790
关键词Ionic liquid Oligomer electrolyte Dye-sensitized solar cells Ionic conductivity Conversion efficiency
ISSN号0927-0248
DOI10.1016/j.solmat.2007.01.009
通讯作者Lin, yuan(linyuan@iccas.ac.cn)
英文摘要Ionic liquid oligomers prepared by incorporating imidazolium ionic liquid with peo oligomers were investigated as electrolytes for dye-sensitized solar cells (dsscs). the influences of peo molecular weight and imidazolium group of the ionic liquid oligomers on the ionic conductivity, apparent diffusion coefficient of the redox species in the electrolytes and the performance of solar cells were examined. the structural effects of the ionic liquid oligomers on the kinetic behaviors of dye regeneration and triiodide reduction reactions taken place at nanocrystalline tio2 electrode and pt counter-electrode, respectively, were further studied by cyclic-voltammetry and electrochemical impedance spectroscopy measurements. the increase of the peo molecular weight of the ionic liquid oligomers results in the faster dye regeneration rate and lower charge transfer resistance of triiodide reduction leading to the improvement of cell performance effectively. (c) 2007 elsevier b.v. all rights reserved.
WOS关键词TEMPERATURE MOLTEN-SALTS ; POLYMER ELECTROLYTES ; PHOTOELECTROCHEMICAL CELLS ; CONVERSION EFFICIENCIES ; SILICA NANOPARTICLES ; GEL ELECTROLYTE ; PERFORMANCE ; LIGHT ; BRUSH
WOS研究方向Energy & Fuels ; Materials Science ; Physics
WOS类目Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000246438500006
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2380028
专题中国科学院大学
通讯作者Lin, Yuan
作者单位1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Wang, Miao,Xiao, Xurui,Zhou, Xiaowen,et al. Investigation of peo-imidazole ionic liquid oligomer electrolytes for dye-sensitized solar cells[J]. Solar energy materials and solar cells,2007,91(9):785-790.
APA Wang, Miao,Xiao, Xurui,Zhou, Xiaowen,Li, Xueping,&Lin, Yuan.(2007).Investigation of peo-imidazole ionic liquid oligomer electrolytes for dye-sensitized solar cells.Solar energy materials and solar cells,91(9),785-790.
MLA Wang, Miao,et al."Investigation of peo-imidazole ionic liquid oligomer electrolytes for dye-sensitized solar cells".Solar energy materials and solar cells 91.9(2007):785-790.
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