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Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composites
Zhang, Junping; Wang, Qin; Wang, Aiqin
刊名Carbohydrate polymers
2007-03-21
卷号68期号:2页码:367-374
关键词Superabsorbent composite Water absorbency Attapulgite Chitosan
ISSN号0144-8617
DOI10.1016/j.carbpol.2006.11.018
通讯作者Wang, aiqin(aqwang@lzb.ac.cn)
英文摘要A novel chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composite with water absorbency of 159.6 g g(-1) in distilled water and 42.3 g g(-1) in 0.9 wt% nacl solution was prepared by graft polymerization with chitosan, acrylic acid and attapulgite in aqueous solution, using n,n'-methylenebisacrylamide as a crosslinker and ammonium persulfate as an initiator. factors influencing water absorbency of the superabsorbent composite were investigated, such as average molecular weight of chitosan, weight ratio of acrylic acid to chitosan, dewatering method, the amount of crosslinker and attapulgite. the result from ftir spectra showed that -oh of attapulgite, -oh, -nhco and -nh2 of chitosan participated in graft polymerization with acrylic acid. the introduced attapulgite enhanced thermal stability of the chitosan-g-poly(acrylic acid) superabsorbent and formed a loose and more porous surface. introducing a small amount of attapulgite also enhanced water absorbency of the chitosan-g-poly(acrylic acid) superabsorbent. (c) 2006 elsevier ltd. all rights reserved.
WOS关键词WATER ABSORBENCY ; SWELLING RATE ; HYDROGELS ; CHITOSAN ; COPOLYMER ; CU(II)
WOS研究方向Chemistry ; Polymer Science
WOS类目Chemistry, Applied ; Chemistry, Organic ; Polymer Science
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000245168800020
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2379990
专题中国科学院大学
通讯作者Wang, Aiqin
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Ecomat & Green Chem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Junping,Wang, Qin,Wang, Aiqin. Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composites[J]. Carbohydrate polymers,2007,68(2):367-374.
APA Zhang, Junping,Wang, Qin,&Wang, Aiqin.(2007).Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composites.Carbohydrate polymers,68(2),367-374.
MLA Zhang, Junping,et al."Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composites".Carbohydrate polymers 68.2(2007):367-374.
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