Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composites | |
Zhang, Junping; Wang, Qin; Wang, Aiqin | |
刊名 | Carbohydrate polymers |
2007-03-21 | |
卷号 | 68期号:2页码:367-374 |
关键词 | Superabsorbent composite Water absorbency Attapulgite Chitosan |
ISSN号 | 0144-8617 |
DOI | 10.1016/j.carbpol.2006.11.018 |
通讯作者 | Wang, aiqin(aqwang@lzb.ac.cn) |
英文摘要 | A novel chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composite with water absorbency of 159.6 g g(-1) in distilled water and 42.3 g g(-1) in 0.9 wt% nacl solution was prepared by graft polymerization with chitosan, acrylic acid and attapulgite in aqueous solution, using n,n'-methylenebisacrylamide as a crosslinker and ammonium persulfate as an initiator. factors influencing water absorbency of the superabsorbent composite were investigated, such as average molecular weight of chitosan, weight ratio of acrylic acid to chitosan, dewatering method, the amount of crosslinker and attapulgite. the result from ftir spectra showed that -oh of attapulgite, -oh, -nhco and -nh2 of chitosan participated in graft polymerization with acrylic acid. the introduced attapulgite enhanced thermal stability of the chitosan-g-poly(acrylic acid) superabsorbent and formed a loose and more porous surface. introducing a small amount of attapulgite also enhanced water absorbency of the chitosan-g-poly(acrylic acid) superabsorbent. (c) 2006 elsevier ltd. all rights reserved. |
WOS关键词 | WATER ABSORBENCY ; SWELLING RATE ; HYDROGELS ; CHITOSAN ; COPOLYMER ; CU(II) |
WOS研究方向 | Chemistry ; Polymer Science |
WOS类目 | Chemistry, Applied ; Chemistry, Organic ; Polymer Science |
语种 | 英语 |
出版者 | ELSEVIER SCI LTD |
WOS记录号 | WOS:000245168800020 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2379990 |
专题 | 中国科学院大学 |
通讯作者 | Wang, Aiqin |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Ecomat & Green Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Junping,Wang, Qin,Wang, Aiqin. Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composites[J]. Carbohydrate polymers,2007,68(2):367-374. |
APA | Zhang, Junping,Wang, Qin,&Wang, Aiqin.(2007).Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composites.Carbohydrate polymers,68(2),367-374. |
MLA | Zhang, Junping,et al."Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composites".Carbohydrate polymers 68.2(2007):367-374. |
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