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	Anion effect on the structural conformation of tetranuclear cadmium(ii) complexes
	Wang, Ruihu; Yuan, Daqiang; Jiang, Feilong; Han, Lei; Gong, Yaqiong; Hong, Maochun
刊名	Crystal growth & design
	2006-06-01
卷号	6期号:6页码:1351-1360
ISSN号	1528-7483
DOI	10.1021/cg0505970
通讯作者	Hong, maochun(hmc@ms.fjirsm.ac.cn)
英文摘要	Six tetranuclear cadmium(ii) complexes, na[cd-4(hmt)(2)(h2o)(6)(dpa)(4)(no3)]center dot 8h(2)o (1), na[cd-4(hmt)(2)(ch3oh)(2)(h2o)(4)(dpa)(4)i]center dot 8h(2)o (2), na[cd-4(hmt)(2)(h2o)(6)(dpa)(4)br]center dot 8h(2)o (3), na-2[cd-4(hmt)(2)(h2o)(6)(dpa)(4)(scn)(2)]center dot 4h(2)o (4), {na[cd-4(hmt)(2)(h2o)(6)(dpa)(4)cl](h2o)(4)}(n) (5), and {[cd-4(hmt)(3)(h2o)(5)(dpa)(4)](h2o)(10)}(n) (6) (hmt=hexamethylenetetramine, h(2)dpa=diphenic acid), were synthesized by reactions of h(2)dpa, hmt, and cdx2 (x=no3-, i-, br-, cl-, scn-, and oac-). all the complexes contain a basic unit [cd-4(dpa)(4)], in which four dpa ligands in a chelating bis-bidentate coordination mode link two six-coordinate and two seven-coordinate cadmium(ii) centers. the research result demonstrates that the nature of the counterions has an important effect on the assembly process of neutral and anionic mixed ligands with metal ions. in 1-3, no3-, i-, or br- bridges the two seven-coordinate cd-ii centers of the unit to form a discrete tetranuclear molecule with a cis-conformation and hmt as a terminal ligand coordinated to each of the two six-coordinate cadmium(ii) centers. two scn- in 4 acting as terminal ligands generate a discrete trans-conformational tetranuclear cluster anion. the hmt in 5 acting as a mu-ligand links cis-conformational tetranuclear units by cd-n bonds to generate a one-dimensional chain structure, while the hmt in 6 acting as a mu-ligand links the tetranuclear units by cd-n bonds to generate a two-dimensional layer structure composed of a planar-conformation [cd-4(dpa)(4)] unit. the fluorescent studies in the solid at room temperature show that the six complexes exhibit strong violet or blue emissions in the range 370-500 nm arising from the charge-transfer transition and that the bridging anions have a significant effect on their fluorescent properties.
WOS关键词	DIFFERENT COORDINATION ARCHITECTURES ; CRYSTAL-STRUCTURES ; HYDROTHERMAL SYNTHESIS ; BRIDGING LIGAND ; SILVER(I)-HEXAMETHYLENETETRAMINE LAYERS ; SUPRAMOLECULAR ARCHITECTURES ; MOLECULAR ARCHITECTURES ; MAGNETIC-PROPERTIES ; SILVER(I) SALTS ; METAL-COMPLEXES
WOS研究方向	Chemistry ; Crystallography ; Materials Science
WOS类目	Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000238097300023
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2379672
专题	中国科学院大学
通讯作者	Hong, Maochun
作者单位	Chinese Acad Sci, Fujian Inst Res Struct Matter, Grad Sch, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
推荐引用方式 GB/T 7714	Wang, Ruihu,Yuan, Daqiang,Jiang, Feilong,et al. Anion effect on the structural conformation of tetranuclear cadmium(ii) complexes[J]. Crystal growth & design,2006,6(6):1351-1360.
APA	Wang, Ruihu,Yuan, Daqiang,Jiang, Feilong,Han, Lei,Gong, Yaqiong,&Hong, Maochun.(2006).Anion effect on the structural conformation of tetranuclear cadmium(ii) complexes.Crystal growth & design,6(6),1351-1360.
MLA	Wang, Ruihu,et al."Anion effect on the structural conformation of tetranuclear cadmium(ii) complexes".Crystal growth & design 6.6(2006):1351-1360.

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