Alkali doped polybenzimidazole membrane for alkaline direct methanol fuel cell
Hou, Hongying1,3; Sun, Gongquan1; He, Ronghuan2; Sun, Baoying2; Jin, Wei1,3; Liu, He1,3; Xin, Qin1
刊名international journal of hydrogen energy
2008-12-01
卷号33期号:23页码:7172-7176
关键词Polybenzimidazole (PBI) Alkali direct methanol fuel cell (ADMFC) Fast kinetics
通讯作者孙公权
产权排序1;1
英文摘要an anion exchange membrane for alkaline direct methanol fuel cell (admfc) was prepared by doping polybenzimidazole(pbi) membrane with koh. the obtained membrane was characterized by means of xrd, tga-dta, ac and so on. the results suggested that it possessed satisfying thermal stability and comparable mechanical strength with acid doped pbi. at room temperature, methanol permeability through this membrane was one order of magnitude lower than that of nafion(r) membrane, while its ionic conductivity was comparable with that of other anion exchange membranes in literatures. for admfc at 90 degrees c based on this pbi/koh membrane electrolyte, the peak power density was about 31 mw/cm(2), which was significantly improved mainly due to this membrane's high thermal stability, fast kinetics of electrochemical reactions and lower methanol permeability. (c) 2008 international association for hydrogen energy. published by elsevier ltd. all rights reserved
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, physical ; electrochemistry ; energy & fuels
研究领域[WOS]chemistry ; electrochemistry ; energy & fuels
关键词[WOS]anion-exchange membranes ; high-temperature pemfc ; electrolyte membranes ; composite membrane ; acid ; conductivity ; ethanol ; model ; films ; dmfc
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000261917900041
公开日期2010-11-30
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/101405]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Direct Alcohol Fuel Cells Lab, Dalian 116023, Peoples R China
2.Northeastern Univ, Shenyang 110004, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Hou, Hongying,Sun, Gongquan,He, Ronghuan,et al. Alkali doped polybenzimidazole membrane for alkaline direct methanol fuel cell[J]. international journal of hydrogen energy,2008,33(23):7172-7176.
APA Hou, Hongying.,Sun, Gongquan.,He, Ronghuan.,Sun, Baoying.,Jin, Wei.,...&Xin, Qin.(2008).Alkali doped polybenzimidazole membrane for alkaline direct methanol fuel cell.international journal of hydrogen energy,33(23),7172-7176.
MLA Hou, Hongying,et al."Alkali doped polybenzimidazole membrane for alkaline direct methanol fuel cell".international journal of hydrogen energy 33.23(2008):7172-7176.
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