Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by samariurn diiodide | |
Niu, Hongying; Guo, Haiming; Yao, He; Wang, Yue; Wang, Gongying | |
刊名 | Journal of molecular catalysis a-chemical |
2006-11-15 | |
卷号 | 259期号:1-2页码:292-295 |
关键词 | Samarium diiodide Transesterification Diphenyl carbonate Dimethyl carbonate |
ISSN号 | 1381-1169 |
DOI | 10.1016/j.molcata.2006.06.040 |
通讯作者 | Wang, gongying(gywang@cioc.ac.cn) |
英文摘要 | Samarium diiodide was found to be a novel and efficient catalyst for the transesterification of phenol and dmc. compared with other catalysts, samarium diiodide can reach high activity with a very low catalyst amount. when the reaction was carried out between 150 and 180 degrees c, with a molar ratio of phenol to dmc of 1: 1, a reaction time 10 h, a catalyst amount 0.2% (molar ratio to phenol), the conversion of phenol was 52.8%, the yield of mpc and dpc was 26.5% and 22.8%, respectively. (c) 2006 elsevier b.v. all rights reserved. |
WOS关键词 | GAS-PHASE TRANSESTERIFICATION ; ORGANIC-SYNTHESIS ; CHEMISTRY ; DIMETHYLCARBONATE ; DIALKYL |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000241924100045 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2379266 |
专题 | 中国科学院大学 |
通讯作者 | Wang, Gongying |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Niu, Hongying,Guo, Haiming,Yao, He,et al. Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by samariurn diiodide[J]. Journal of molecular catalysis a-chemical,2006,259(1-2):292-295. |
APA | Niu, Hongying,Guo, Haiming,Yao, He,Wang, Yue,&Wang, Gongying.(2006).Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by samariurn diiodide.Journal of molecular catalysis a-chemical,259(1-2),292-295. |
MLA | Niu, Hongying,et al."Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by samariurn diiodide".Journal of molecular catalysis a-chemical 259.1-2(2006):292-295. |
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