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Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by samariurn diiodide
Niu, Hongying; Guo, Haiming; Yao, He; Wang, Yue; Wang, Gongying
刊名Journal of molecular catalysis a-chemical
2006-11-15
卷号259期号:1-2页码:292-295
关键词Samarium diiodide Transesterification Diphenyl carbonate Dimethyl carbonate
ISSN号1381-1169
DOI10.1016/j.molcata.2006.06.040
通讯作者Wang, gongying(gywang@cioc.ac.cn)
英文摘要Samarium diiodide was found to be a novel and efficient catalyst for the transesterification of phenol and dmc. compared with other catalysts, samarium diiodide can reach high activity with a very low catalyst amount. when the reaction was carried out between 150 and 180 degrees c, with a molar ratio of phenol to dmc of 1: 1, a reaction time 10 h, a catalyst amount 0.2% (molar ratio to phenol), the conversion of phenol was 52.8%, the yield of mpc and dpc was 26.5% and 22.8%, respectively. (c) 2006 elsevier b.v. all rights reserved.
WOS关键词GAS-PHASE TRANSESTERIFICATION ; ORGANIC-SYNTHESIS ; CHEMISTRY ; DIMETHYLCARBONATE ; DIALKYL
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000241924100045
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2379266
专题中国科学院大学
通讯作者Wang, Gongying
作者单位1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Niu, Hongying,Guo, Haiming,Yao, He,et al. Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by samariurn diiodide[J]. Journal of molecular catalysis a-chemical,2006,259(1-2):292-295.
APA Niu, Hongying,Guo, Haiming,Yao, He,Wang, Yue,&Wang, Gongying.(2006).Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by samariurn diiodide.Journal of molecular catalysis a-chemical,259(1-2),292-295.
MLA Niu, Hongying,et al."Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by samariurn diiodide".Journal of molecular catalysis a-chemical 259.1-2(2006):292-295.
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