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	Syntheses and structures of two copper compounds supported by octamolybdate
	Chen Shu-Mei; Lu Can-Zhong; Chen Li-Juan; Meng Ze-Rong; Zhao Zhen-Guo
刊名	Chinese journal of structural chemistry
	2006
卷号	25期号:12页码:1465-1470
关键词	Beta-octamolybdate Crystal structure Copper complex
ISSN号	0254-5861
通讯作者	Lu can-zhong(czlu@fjirsm.ac.cn)
英文摘要	[{cu(phen)(dmf)(2)}(2)(beta-mo8o26)] 1 (c36h44cu2mo8n8o30, m-r = 1963.39, phen = 1,10-phenanthrohne) and [cu-1(phen)(2)](2)[{cu-1(phen)}(2)mo-8\o-26] 2 (c72h48cu4mo8n12o26, m-r = 2518.90) have been synthesized from (bu4n)(2)[mo6o19], cu(no3)(2)center dot 3h(2)o and phen using solution method and under solvothermal condition, respectively. both compounds i and 2 are structurally, characterized by elemental analyses, ir and single-crystal x-ray diffraction. compound 1 crystallizes in the monoclinic system, space group p2(1)/n, with a = 16.3347(13), b = 9.861(1), c = 17.2827(14) angstrom, beta = g/cm(3) 99.099(4)degrees, v = 2748.8(3) angstrom(3), z = 2, d-c. 2.372, g/cm(3), f(000) = 1900 and mu = 2.614 mm(-1). x-ray diffraction analysis reveals that compound i consists of discrete {[cu(phen)(dmf)(2)](2)(beta-mo8o26)} clusters constructed from beta-[mo8o26](4-) subunits covalently bound to two [cu(phen)(dmf)(2)](2c) coordination groups. compound 2 crystallizes in the monoclinic system, space group c2/c, with a = 33.1401(9), b = 16.4508(5), c = 16.2622(4) angstrom, beta = 119.2460(10)degrees, v = 7735.7(4) angstrom(3), z = 4, d-c = 2.163 g/cm(3), f(000) = 4896 and mu = 2.413 mm(-1). x-ray diffraction analysis reveals that compound 2 consists of a centrosymmetric, beta-octamolybdate-supported complex anion [{cu(phen)}(2)mo8o26] and two bis-phenanthroline cu(i) cations.
WOS关键词	HYDROTHERMAL SYNTHESIS ; COMPLEX ; CHEMISTRY
WOS研究方向	Chemistry ; Crystallography
WOS类目	Chemistry, Inorganic & Nuclear ; Crystallography
语种	英语
出版者	CHINESE JOURNAL STRUCTURAL CHEMISTRY
WOS记录号	WOS:000243087800009
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2378896
专题	中国科学院大学
通讯作者	Lu Can-Zhong
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Chen Shu-Mei,Lu Can-Zhong,Chen Li-Juan,et al. Syntheses and structures of two copper compounds supported by octamolybdate[J]. Chinese journal of structural chemistry,2006,25(12):1465-1470.
APA	Chen Shu-Mei,Lu Can-Zhong,Chen Li-Juan,Meng Ze-Rong,&Zhao Zhen-Guo.(2006).Syntheses and structures of two copper compounds supported by octamolybdate.Chinese journal of structural chemistry,25(12),1465-1470.
MLA	Chen Shu-Mei,et al."Syntheses and structures of two copper compounds supported by octamolybdate".Chinese journal of structural chemistry 25.12(2006):1465-1470.

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