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Structure and thermal expansion properties of solid solution nd2-xerxw3o12 (0.0 <= x <= 0.6 and 1.5 <= x <= 2.0)
Wu, MM; Peng, J; Cheng, YZ; Wang, H; Yu, ZX; Chen, DF; Hu, ZB
刊名Solid state sciences
2006-06-01
卷号8期号:6页码:665-670
关键词Thermal expansion Tungstates Neutron powder diffraction X-ray diffraction
ISSN号1293-2558
DOI10.1016/j.solidstatesciences.2006.02.030
通讯作者Hu, zb()
英文摘要Solid solutions of nd2-xerxw3o12 (0.0 <= x <= 0.6 and 1.5 <= x <= 2.0) have been successfully prepared and their structures have been investigated by x-ray and neutron powder diffraction. the thermal expansion properties of nd2-xerxw3o12 (x = 0.2, 0.4, 1.5, 1.7 and 1.9) were studied with high temperature x-ray diffraction. positive thermal expansions of compounds nd2-xerxw3o12 with 0.0 <= x <= 0.6 are found to be anisotropic along the three crystallographic directions where the a-axis expands in the 25-200 degrees c range and contracts in the 200-800 degrees c range, while b- and c-axes show expansion in the whole temperature range. negative thermal expansion coefficient alpha(l) of compounds nd2-xerxw3o12 with 1.5 <= x <= 2.0 becomes more negative from -6.032 x 10(-6) to -6.28 x 10(-6)degrees c-1 with the neodymium content increasing. (c) 2006 elsevier sas. all rights reserved.
WOS关键词BOND-VALENCE PARAMETERS ; CRYSTAL-STRUCTURE ; PHASE-TRANSITION ; TUNGSTATE ; SC-2(WO4)(3) ; DIFFRACTION ; Y2W3O12 ; ZRW2O8
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Inorganic & Nuclear ; Chemistry, Physical ; Physics, Condensed Matter
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000238274700013
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2378715
专题中国科学院大学
通讯作者Hu, ZB
作者单位1.Chinese Acad Sci, Grad Sch, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
2.China Inst Atom Energy, Beijing 102413, Peoples R China
推荐引用方式
GB/T 7714
Wu, MM,Peng, J,Cheng, YZ,et al. Structure and thermal expansion properties of solid solution nd2-xerxw3o12 (0.0 <= x <= 0.6 and 1.5 <= x <= 2.0)[J]. Solid state sciences,2006,8(6):665-670.
APA Wu, MM.,Peng, J.,Cheng, YZ.,Wang, H.,Yu, ZX.,...&Hu, ZB.(2006).Structure and thermal expansion properties of solid solution nd2-xerxw3o12 (0.0 <= x <= 0.6 and 1.5 <= x <= 2.0).Solid state sciences,8(6),665-670.
MLA Wu, MM,et al."Structure and thermal expansion properties of solid solution nd2-xerxw3o12 (0.0 <= x <= 0.6 and 1.5 <= x <= 2.0)".Solid state sciences 8.6(2006):665-670.
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