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	Synthesis and crystal structures of four novel mo(w)/cu/s polymers containing thiolato bridging ligands
	Li, JR; Du, SS; Wu, XT
刊名	Journal of cluster science
	2005-12-01
卷号	16期号:4页码:489-500
关键词	Tetrathiotungstate Tetrathiomolybdate Mo(w)/cu/s polymers Thiolato ligands Crystal structures
ISSN号	1040-7278
DOI	10.1007/s10876-005-0012-2
通讯作者	Du, ss()
英文摘要	Four novel m/cu/s polymers [et4n][ms4cu3(s2coet)(2)] (1a: m=mo; 1b: m=w) and et4n][ms4cu2set] (2a: m=mo; 2b: m=w) have been prepared by reactions of [et4n](2)[ms4] with cus2coet and cuset. x-ray crystal structure determinations reveal that the polymeric anions of complexes 1a and 1b both consist of ms4cu3 building blocks linked via bidentate [s2coet](-) bridging ligands to form 1d polymeric chains. the anion structures of the polymeric compounds 2a and 2b contain ms4cu2 repeating units which are connected via mu-set- ligands forming a zigzag chain running down the crystallographic b axis.
WOS关键词	HETEROBIMETALLIC CLUSTERS ; COPPER(I) ; COMPLEX ; THIOTUNGSTATES ; THIOMOLYBDATES ; CHEMISTRY ; TUNGSTEN ; SPECTRA ; MOIETY ; CHAIN
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	SPRINGER/PLENUM PUBLISHERS
WOS记录号	WOS:000235749400002
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2378374
专题	中国科学院大学
通讯作者	Du, SS
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Li, JR,Du, SS,Wu, XT. Synthesis and crystal structures of four novel mo(w)/cu/s polymers containing thiolato bridging ligands[J]. Journal of cluster science,2005,16(4):489-500.
APA	Li, JR,Du, SS,&Wu, XT.(2005).Synthesis and crystal structures of four novel mo(w)/cu/s polymers containing thiolato bridging ligands.Journal of cluster science,16(4),489-500.
MLA	Li, JR,et al."Synthesis and crystal structures of four novel mo(w)/cu/s polymers containing thiolato bridging ligands".Journal of cluster science 16.4(2005):489-500.

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