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	Syntheses and crystal structures of the first organically templated metal tellurites
	Feng, ML; Mao, JG
刊名	Journal of solid state chemistry
	2005-07-01
卷号	178期号:7页码:2256-2261
关键词	Layered compounds Hydrothermal reactions Crystal structures Organically templated
ISSN号	0022-4596
DOI	10.1016/j.jssc.2005.05.005
通讯作者	Mao, jg(mjg@ms.fjirsm.ac.cn)
英文摘要	The first organically templated vanadium tellurites. [h(2)en][(vo2)(teo3)](2)center dot h2o (1, en = ethylenediamine) and [h(2)pip][(vo2) (teo3)](2) (2, pip = piperazine) have been synthesized by hydrothermal reactions and structurally characterized, both compounds feature a [(vo2)(teo3)](-) anionic layer containing v2te2 four-member rings and v4te4 eight member rings, the vanadium (v) atom is five coordinated by three tellurite oxygens and two terminal oxygen atoms in a distorted trigonal bipyramidal geometry. the interconnection of the vo5 polyhedra by bridging tellurite groups leads to a 2d corrugated anionic inorganic layer, the doubly protonated template cations and the lattice water molecules in i are located at the interlayer space and are involved in hydrogen bonding. the doubly protonated template cation in 2 is not involved in hydrogen bonding with the anionic inorganic layer. (c) 2005 elsevier inc. all rights reserved.
WOS关键词	BOND-VALENCE PARAMETERS ; HYDROTHERMAL SYNTHESIS ; VANADIUM SELENITES ; DIMENSIONAL TELLURITES ; GLASSES ; MOLYBDENUM(VI) ; NH4 ; RB ; NI
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear ; Chemistry, Physical
语种	英语
出版者	ACADEMIC PRESS INC ELSEVIER SCIENCE
WOS记录号	WOS:000230695200012
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2378276
专题	中国科学院大学
通讯作者	Mao, JG
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Fujian 350002, Peoples R China
推荐引用方式 GB/T 7714	Feng, ML,Mao, JG. Syntheses and crystal structures of the first organically templated metal tellurites[J]. Journal of solid state chemistry,2005,178(7):2256-2261.
APA	Feng, ML,&Mao, JG.(2005).Syntheses and crystal structures of the first organically templated metal tellurites.Journal of solid state chemistry,178(7),2256-2261.
MLA	Feng, ML,et al."Syntheses and crystal structures of the first organically templated metal tellurites".Journal of solid state chemistry 178.7(2005):2256-2261.

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