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	Nitrosyl isocyanate (onnco): gas-phase generation and a hel photoelectron spectroscopy study
	Zeng, XQ; Ge, MF; Sun, Z; Wang, DX
刊名	Inorganic chemistry
	2005-12-12
卷号	44期号:25页码:9283-9287
ISSN号	0020-1669
DOI	10.1021/ic051349w
通讯作者	Wang, dx(gemaofa@iccas.ac.cn)
英文摘要	The nitrosyl isocyanate (onnco) has been generated from a heterogeneous reaction of gaseous nitrosyl chloride with silver isocyanate and studied for the first time in the gas phase. this structurally and energetically novel transient specimen is characterized by hel photoelectron spectroscopy combined with dft calculations. both the calculations and the spectroscopic results suggest that the molecule adopts an open-chain trans structure. the observed decomposition products indicate the formation of onnco and further confirm the previously reported decomposition pathway.
WOS关键词	NCO+NO REACTION ; ELECTRONIC STATES ; AB-INITIO ; ENERGY ; NO ; NITROGEN ; SPECTRA ; CYANIDE ; AZIDE ; RADICALS
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000233796800024
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2378254
专题	中国科学院大学
通讯作者	Wang, DX
作者单位	1.Chinese Acad Sci, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Zeng, XQ,Ge, MF,Sun, Z,et al. Nitrosyl isocyanate (onnco): gas-phase generation and a hel photoelectron spectroscopy study[J]. Inorganic chemistry,2005,44(25):9283-9287.
APA	Zeng, XQ,Ge, MF,Sun, Z,&Wang, DX.(2005).Nitrosyl isocyanate (onnco): gas-phase generation and a hel photoelectron spectroscopy study.Inorganic chemistry,44(25),9283-9287.
MLA	Zeng, XQ,et al."Nitrosyl isocyanate (onnco): gas-phase generation and a hel photoelectron spectroscopy study".Inorganic chemistry 44.25(2005):9283-9287.

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