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	Catalytie preparation of methyl formate from methanol over silver
	Yang, Z; Li, J; Yang, XG; Wu, Y
刊名	Chemical research in chinese universities
	2005-09-01
卷号	21期号:5页码:573-576
关键词	Silver Methanol Methyl formate Oxygen species Synergistic effect
ISSN号	1005-9040
通讯作者	Yang, xg()
英文摘要	A catalytic reaction over a silver catalyst performed in an unregarded temperature region(473-873 k), with a long catalytic lifetime for the production of methyl formate from methanol was provided. as a potential preparing route. the optimal yield of methyl formate(ca. 14.8%) with a selectivity > 90% was obtained at about 573 k. because alpha-oxygen species and bulk oxygen species coexist in the unregarded temperature region, a synergistic process concerning alpha-oxygen species and bulk oxygen species was proved over o-alpha-rich and o-gamma-rich samples.
WOS关键词	ELECTROLYTIC SILVER ; PARTIAL OXIDATION ; DEHYDROGENATION ; OXYGEN ; CARBONYLATION ; FORMALDEHYDE ; ETHYLENE ; MODEL ; RAMAN ; TPD
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	HIGHER EDUCATION PRESS
WOS记录号	WOS:000232473700017
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2378045
专题	中国科学院大学
通讯作者	Yang, XG
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Yang, Z,Li, J,Yang, XG,et al. Catalytie preparation of methyl formate from methanol over silver[J]. Chemical research in chinese universities,2005,21(5):573-576.
APA	Yang, Z,Li, J,Yang, XG,&Wu, Y.(2005).Catalytie preparation of methyl formate from methanol over silver.Chemical research in chinese universities,21(5),573-576.
MLA	Yang, Z,et al."Catalytie preparation of methyl formate from methanol over silver".Chemical research in chinese universities 21.5(2005):573-576.

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