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Luminescent lanthanide selenites and tellurites decorated by moo4 tetrahedra or moo6 octahedra: nd2mose2o10, gd2mose3o12, la2mote3o12, and nd2mote3o12
Shen, YL; Jiang, HL; Xu, J; Mao, JG; Cheah, KW
刊名Inorganic chemistry
2005-12-12
卷号44期号:25页码:9314-9321
ISSN号0020-1669
DOI10.1021/ic051376m
通讯作者Mao, jg()
英文摘要Solid state reactions of lanthanicle oxide, moo3 and seo2 (or teo2) at high temperature in an evacuated quartz tube lead to four new ln-mo-se(te)-o quaternary phases with four different types of structures, namely, nd2mose2o10, gd2mose3o12, la2mote3o12, and nd2mote3o12. the structure of nd2mose2o10 features a 3d architecture built by the intergrowth of the nd-se-o layers with the nd-mo-o layers. the structure of gd2mose3o12 contains a 3d network of gadolinium selenite with the moo6 octahedra occupying the cavities of the structure. the structure of la2mote3o12 features a 3d network of la-2(te3o8)(2+) with the tunnels along the a axis occupied by the moo4 tetrahedra. nd2mote3o12 features a 2d layer built by the lanthanide ions interconnected by tellurite groups and ditellurite groups, with the moo4 tetrahedra as the interlayer pendant groups. room temperature and low temperature luminescent studies indicate that nd2mose2o10 and nd2mote3o12 exhibit strong luminescence in the near-ir region.
WOS关键词CRYSTAL-STRUCTURE ; TRANSITION-METAL ; COMPLEXES ; CATIONS
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000233796800029
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2378032
专题中国科学院大学
通讯作者Mao, JG
作者单位1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
2.Chinese Acad Sci, Grad Sch, Fujian 350002, Peoples R China
3.Hong Kong Baptist Univ, Dept Phys, Ctr Adv Luminescence Mat, Hong Kong, Hong Kong, Peoples R China
推荐引用方式
GB/T 7714
Shen, YL,Jiang, HL,Xu, J,et al. Luminescent lanthanide selenites and tellurites decorated by moo4 tetrahedra or moo6 octahedra: nd2mose2o10, gd2mose3o12, la2mote3o12, and nd2mote3o12[J]. Inorganic chemistry,2005,44(25):9314-9321.
APA Shen, YL,Jiang, HL,Xu, J,Mao, JG,&Cheah, KW.(2005).Luminescent lanthanide selenites and tellurites decorated by moo4 tetrahedra or moo6 octahedra: nd2mose2o10, gd2mose3o12, la2mote3o12, and nd2mote3o12.Inorganic chemistry,44(25),9314-9321.
MLA Shen, YL,et al."Luminescent lanthanide selenites and tellurites decorated by moo4 tetrahedra or moo6 octahedra: nd2mose2o10, gd2mose3o12, la2mote3o12, and nd2mote3o12".Inorganic chemistry 44.25(2005):9314-9321.
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