Cornucopian cylindrical aggregate morphologies from self-assembly of amphiphilic triblock copolymer in selective media | |
Jiang, Y; Zhu, JT; Jiang, W; Liang, HJ | |
刊名 | Journal of physical chemistry b |
2005-11-24 | |
卷号 | 109期号:46页码:21549-21555 |
ISSN号 | 1520-6106 |
DOI | 10.1021/jp052420m |
通讯作者 | Jiang, w() |
英文摘要 | We have investigated, both experimentally and theoretically, the aggregation of aba amphiphilic triblock copolymers in dilute solution. we observed a number of complex architectures having toroidal and network structures, including some novel ones. the computational analyses of these systems offer some insight into the origins of the self-assembly of these amphiphiles. the results we obtained using real-space self-consistent field theory reveal that the formation of network and toroidal structures from the block copolymers occurs as the result of the breaking of "inhomogeneous vesicles"; the observed polymorphism results from the existence of multiple metastable states. |
WOS关键词 | ACID) BLOCK-COPOLYMERS ; DILUTE-SOLUTION ; DIBLOCK COPOLYMERS ; FIELD-THEORY ; MICELLES ; POLYMERS ; VESICLES ; SURFACTANTS ; OXIDE) ; FLUIDS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000233437100015 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2377856 |
专题 | 中国科学院大学 |
通讯作者 | Jiang, W |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 13022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China 3.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China 4.Univ Sci & Technol China, Dept Polymer Sci & Engn, Hefei 230026, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang, Y,Zhu, JT,Jiang, W,et al. Cornucopian cylindrical aggregate morphologies from self-assembly of amphiphilic triblock copolymer in selective media[J]. Journal of physical chemistry b,2005,109(46):21549-21555. |
APA | Jiang, Y,Zhu, JT,Jiang, W,&Liang, HJ.(2005).Cornucopian cylindrical aggregate morphologies from self-assembly of amphiphilic triblock copolymer in selective media.Journal of physical chemistry b,109(46),21549-21555. |
MLA | Jiang, Y,et al."Cornucopian cylindrical aggregate morphologies from self-assembly of amphiphilic triblock copolymer in selective media".Journal of physical chemistry b 109.46(2005):21549-21555. |
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