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Cornucopian cylindrical aggregate morphologies from self-assembly of amphiphilic triblock copolymer in selective media
Jiang, Y; Zhu, JT; Jiang, W; Liang, HJ
刊名Journal of physical chemistry b
2005-11-24
卷号109期号:46页码:21549-21555
ISSN号1520-6106
DOI10.1021/jp052420m
通讯作者Jiang, w()
英文摘要We have investigated, both experimentally and theoretically, the aggregation of aba amphiphilic triblock copolymers in dilute solution. we observed a number of complex architectures having toroidal and network structures, including some novel ones. the computational analyses of these systems offer some insight into the origins of the self-assembly of these amphiphiles. the results we obtained using real-space self-consistent field theory reveal that the formation of network and toroidal structures from the block copolymers occurs as the result of the breaking of "inhomogeneous vesicles"; the observed polymorphism results from the existence of multiple metastable states.
WOS关键词ACID) BLOCK-COPOLYMERS ; DILUTE-SOLUTION ; DIBLOCK COPOLYMERS ; FIELD-THEORY ; MICELLES ; POLYMERS ; VESICLES ; SURFACTANTS ; OXIDE) ; FLUIDS
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000233437100015
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2377856
专题中国科学院大学
通讯作者Jiang, W
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 13022, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
3.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
4.Univ Sci & Technol China, Dept Polymer Sci & Engn, Hefei 230026, Anhui, Peoples R China
推荐引用方式
GB/T 7714
Jiang, Y,Zhu, JT,Jiang, W,et al. Cornucopian cylindrical aggregate morphologies from self-assembly of amphiphilic triblock copolymer in selective media[J]. Journal of physical chemistry b,2005,109(46):21549-21555.
APA Jiang, Y,Zhu, JT,Jiang, W,&Liang, HJ.(2005).Cornucopian cylindrical aggregate morphologies from self-assembly of amphiphilic triblock copolymer in selective media.Journal of physical chemistry b,109(46),21549-21555.
MLA Jiang, Y,et al."Cornucopian cylindrical aggregate morphologies from self-assembly of amphiphilic triblock copolymer in selective media".Journal of physical chemistry b 109.46(2005):21549-21555.
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