Co oxidation over the perovskite-like oxides la2-xsrxmo4 (x=0.0, 0.5, 1.0; m = cu, ni): a study from cyclic voltammetry | |
Zhu, JJ; Zhao, Z; Xiao, DH; Li, J; Yang, XG; Wu, Y | |
刊名 | Zeitschrift fur physikalische chemie-international journal of research in physical chemistry & chemical physics
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2005 | |
卷号 | 219期号:6页码:807-815 |
关键词 | Perovskite-like oxides La2-xsrxcuo4 Cyclic voltammetry Co oxidation |
ISSN号 | 0942-9352 |
通讯作者 | Yang, xg() |
英文摘要 | Correlations between the catalytic performance and the electrochemical properties in heterogeneous catalysis were observed, using perovskite-like oxides la2-xsrxmo4 (x = 0.0, 0.5, 1.0, m=cu, ni) as the model catalysts and co oxidation as the probe reaction. for a reaction that contains reducing agent in the feed gas, the activity depends mainly on the area of redox peak in the cv curves, while has no much relation to the symmetry of the redox potentials. the irreversible cycle in the first cv curves of lasrcuo4 suggested that the first step of the reaction is adsorption, corresponding to mn+ (cu2+) to m(n+1)+ (cu3+). |
WOS关键词 | CATALYTIC PROPERTIES ; REDUCTION ; DECOMPOSITION ; LAMEO3 ; NO |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
出版者 | OLDENBOURG VERLAG |
WOS记录号 | WOS:000230029100004 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2377790 |
专题 | 中国科学院大学 |
通讯作者 | Yang, XG |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Environm Catalysis Lab, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Beijing Univ Petr, State Key Lab Heavy Oil Proc, Beijing, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, JJ,Zhao, Z,Xiao, DH,et al. Co oxidation over the perovskite-like oxides la2-xsrxmo4 (x=0.0, 0.5, 1.0; m = cu, ni): a study from cyclic voltammetry[J]. Zeitschrift fur physikalische chemie-international journal of research in physical chemistry & chemical physics,2005,219(6):807-815. |
APA | Zhu, JJ,Zhao, Z,Xiao, DH,Li, J,Yang, XG,&Wu, Y.(2005).Co oxidation over the perovskite-like oxides la2-xsrxmo4 (x=0.0, 0.5, 1.0; m = cu, ni): a study from cyclic voltammetry.Zeitschrift fur physikalische chemie-international journal of research in physical chemistry & chemical physics,219(6),807-815. |
MLA | Zhu, JJ,et al."Co oxidation over the perovskite-like oxides la2-xsrxmo4 (x=0.0, 0.5, 1.0; m = cu, ni): a study from cyclic voltammetry".Zeitschrift fur physikalische chemie-international journal of research in physical chemistry & chemical physics 219.6(2005):807-815. |
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