Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system | |
Yang, Z; Li, J; Yang, XG; Wu, Y | |
刊名 | Catalysis letters
![]() |
2005-04-01 | |
卷号 | 100期号:3-4页码:205-211 |
关键词 | Formaldehyde Methanol Methyl formate Oxygen species Silver Synergic effect |
ISSN号 | 1011-372X |
DOI | 10.1007/s10562-004-3457-2 |
通讯作者 | Yang, xg() |
英文摘要 | Catalytic reaction was performed in the unregarded temperature region over silver catalysts with long catalytic lifetime for the conversion of methanol to methyl formate. o-alpha-saturated or o-gamma-saturated silver catalysts were studied individually to identify the roles of o-alpha, o-gamma in the oxidative esterification of methanol over an unsupported polycrystalline silver catalyst. a synergic process is proposed based on the coexistence of alpha-oxygen species and gamma-oxygen species on the surface of polycrystalline silver at about 573 k. |
WOS关键词 | IN-SITU RAMAN ; SELECTIVE OXIDATION ; POLYCRYSTALLINE SILVER ; ELECTROLYTIC SILVER ; SUBSURFACE OXYGEN ; FORMALDEHYDE ; DEHYDROGENATION ; MECHANISM ; ETHYLENE |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
出版者 | SPRINGER |
WOS记录号 | WOS:000228226800015 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2377101 |
专题 | 中国科学院大学 |
通讯作者 | Yang, XG |
作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, Lab Mat & Devices, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Z,Li, J,Yang, XG,et al. Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system[J]. Catalysis letters,2005,100(3-4):205-211. |
APA | Yang, Z,Li, J,Yang, XG,&Wu, Y.(2005).Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system.Catalysis letters,100(3-4),205-211. |
MLA | Yang, Z,et al."Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system".Catalysis letters 100.3-4(2005):205-211. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论