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	Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system
	Yang, Z; Li, J; Yang, XG; Wu, Y
刊名	Catalysis letters
	2005-04-01
卷号	100期号:3-4页码:205-211
关键词	Formaldehyde Methanol Methyl formate Oxygen species Silver Synergic effect
ISSN号	1011-372X
DOI	10.1007/s10562-004-3457-2
通讯作者	Yang, xg()
英文摘要	Catalytic reaction was performed in the unregarded temperature region over silver catalysts with long catalytic lifetime for the conversion of methanol to methyl formate. o-alpha-saturated or o-gamma-saturated silver catalysts were studied individually to identify the roles of o-alpha, o-gamma in the oxidative esterification of methanol over an unsupported polycrystalline silver catalyst. a synergic process is proposed based on the coexistence of alpha-oxygen species and gamma-oxygen species on the surface of polycrystalline silver at about 573 k.
WOS关键词	IN-SITU RAMAN ; SELECTIVE OXIDATION ; POLYCRYSTALLINE SILVER ; ELECTROLYTIC SILVER ; SUBSURFACE OXYGEN ; FORMALDEHYDE ; DEHYDROGENATION ; MECHANISM ; ETHYLENE
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000228226800015
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2377101
专题	中国科学院大学
通讯作者	Yang, XG
作者单位	Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, Lab Mat & Devices, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Yang, Z,Li, J,Yang, XG,et al. Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system[J]. Catalysis letters,2005,100(3-4):205-211.
APA	Yang, Z,Li, J,Yang, XG,&Wu, Y.(2005).Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system.Catalysis letters,100(3-4),205-211.
MLA	Yang, Z,et al."Catalytic oxidation of methanol to methyl formate over silver - a new purpose of a traditional catalysis system".Catalysis letters 100.3-4(2005):205-211.

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