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	Synthesis, structural characterization and magnetic properties of {[gd(dmf)(3)(dmso)(h2o)(3)](mu-cn)[fe(cn)(5)]}center dot 2h(2)o
	Chen, WT; Cai, LZ; Wu, AQ; Guo, GC; Huang, JS; Dong, ZC; Matsushita, A
刊名	Chinese journal of inorganic chemistry
	2004-06-01
卷号	20期号:6页码:693-697
关键词	Crystal structure Cyano-bridged dinuclear complex Hybrid prussian blue complex Molecular magnet Lanthanide mixed ligand complex
ISSN号	1001-4861
通讯作者	Guo, gc()
英文摘要	A new cyano-bridged gadolinium(iii)-iron(iii) complex {[gd(dmf)(3)(dmso)(h2o)(3)](mu-cn)[fe(cn)(5)]} (.) 2h(2)o (dmf= n,n-dimethylformamide; dmso=dimethylsulfoxide) was synthesized by the grinding reaction method. it crystallizes in the triclinic, space group p(1) over bar with cell parameters: a=0.903 63(2) nm, b=1.250 78(3) rim, c=1.413 03(l) nm, alpha=93.174(1)degrees, beta=94.406(1)degrees, gamma=91.917(2)degrees, and v=1.588 87(5) nm(3), d-c=1.592 g(.)cm(-3), z=2, m-r=756.72, f(000)=760, mu=2.645 mm(-1). the slightly distorted square-antiprism eightfold-coordinated gd(iii) and the approximately oriented octahedrally sixfold-coordinated fe(iii) are linked by a cyano-bridge group to construct a dinuclear compound. the {[gd(dmf)(3)(dmso)(h2o)(3)](mu-cn)[fe(cn)(5)]} species are held together via hydrogen bonds to form a three-dimensional framework. the gd(iii)-fe(iii) interaction is antiferromagnetic.
WOS关键词	CYANO-BRIDGED COMPLEXES ; ONE-DIMENSIONAL CHAIN ; CRYSTAL-STRUCTURE ; BUILDING-BLOCKS ; COORDINATION POLYMERS ; TEMPERATURE ; HEXACYANOFERRATE(III) ; MAGNETOCHEMISTRY ; BEHAVIOR ; BETAINE
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	CHINESE CHEMICAL SOCIETY
WOS记录号	WOS:000221754400015
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2376892
专题	中国科学院大学
通讯作者	Guo, GC
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan
推荐引用方式 GB/T 7714	Chen, WT,Cai, LZ,Wu, AQ,et al. Synthesis, structural characterization and magnetic properties of {[gd(dmf)(3)(dmso)(h2o)(3)](mu-cn)[fe(cn)(5)]}center dot 2h(2)o[J]. Chinese journal of inorganic chemistry,2004,20(6):693-697.
APA	Chen, WT.,Cai, LZ.,Wu, AQ.,Guo, GC.,Huang, JS.,...&Matsushita, A.(2004).Synthesis, structural characterization and magnetic properties of {[gd(dmf)(3)(dmso)(h2o)(3)](mu-cn)[fe(cn)(5)]}center dot 2h(2)o.Chinese journal of inorganic chemistry,20(6),693-697.
MLA	Chen, WT,et al."Synthesis, structural characterization and magnetic properties of {[gd(dmf)(3)(dmso)(h2o)(3)](mu-cn)[fe(cn)(5)]}center dot 2h(2)o".Chinese journal of inorganic chemistry 20.6(2004):693-697.

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