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	Stable porphyrin zr and hf metal-organic frameworks featuring 2.5 nm cages: high surface areas, scsc transformations and catalyses
	Zheng, Jun1,2; Wu, Mingyan1; Jiang, Feilong1; Su, Weiping1; Hong, Maochun1
刊名	Chemical science
	2015
卷号	6期号:6页码:3466-3470
ISSN号	2041-6520
DOI	10.1039/c5sc00213c
通讯作者	Wu, mingyan(wumy@fjirsm.ac.cn)
英文摘要	Two isostructural porphyrin zr and hf metal-organic frameworks (fji-h6 and fji-h7) are rationally synthesized, and are constructed from 2.5 nm cubic cages. notably, they both possess high water and chemical stability and can undergo single-crystal to single-crystal transformations to embed cu2+ ions into the open porphyrin rings. fji-h6 has a high bet surface area of 5033 m(2) g(-1). additionally, they exhibit promising catalytic abilities to convert co2 and epoxides into cyclic carbonates at ambient conditions.
WOS关键词	GAS-STORAGE CAPACITIES ; WATER OXIDATION ; CO2 ADSORPTION ; STABILITY ; TOPOLOGY ; DERIVATIVES ; EFFICIENT ; HYDROGEN ; UIO-66 ; PHOTOCATALYSIS
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000354815600026
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2376571
专题	中国科学院大学
通讯作者	Wu, Mingyan
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zheng, Jun,Wu, Mingyan,Jiang, Feilong,et al. Stable porphyrin zr and hf metal-organic frameworks featuring 2.5 nm cages: high surface areas, scsc transformations and catalyses[J]. Chemical science,2015,6(6):3466-3470.
APA	Zheng, Jun,Wu, Mingyan,Jiang, Feilong,Su, Weiping,&Hong, Maochun.(2015).Stable porphyrin zr and hf metal-organic frameworks featuring 2.5 nm cages: high surface areas, scsc transformations and catalyses.Chemical science,6(6),3466-3470.
MLA	Zheng, Jun,et al."Stable porphyrin zr and hf metal-organic frameworks featuring 2.5 nm cages: high surface areas, scsc transformations and catalyses".Chemical science 6.6(2015):3466-3470.

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