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Cyclic phase transition from hexagonal to orthorhombic then back to hexagonal of euf3 while loading uniaxial pressure and under high temperature
Sui, Zhilei1; Wu, Jizhou1; Wang, Xiangqi1; Dai, Rucheng2; Wang, Zhongping2; Zheng, Xianxu3; Zhang, Zengming2,4
刊名Journal of physical chemistry c
2016-08-25
卷号120期号:33页码:18780-18787
ISSN号1932-7447
DOI10.1021/acs.jpcc.6b05907
通讯作者Zheng, xianxu(zxxgoal109@sina.com) ; Zhang, zengming(zzm@ustc.edu.cn)
英文摘要The structure and photoluminescence properties are investigated under high pressure and high temperature for pure orthorhombic and hexagonal euf3 nanocrystals. under hydrostatic compression, the hexagonal euf3 remains stable at pressures up to 26 gpa. under nonhydrostatic compression, a cyclic phase transition from hexagonal to orthorhombic and then back to hexagonal is observed for the first time. when loading uniaxial compression, the pure hexagonal euf3 partly transforms to orthorhombic at 70 mpa, then the orthorhombic euf3 transforms to hexagonal at about 3 gpa, and the transition is completed at about 10 gpa. the cyclic phase transition is also observed during the heating process; the hexagonal transforms to orthorhombic at 550 degrees c and then to hexagonal at 855 degrees c. the content phase diagrams are obtained under high pressure and at high temperature.
WOS关键词PHOTOLUMINESCENCE PROPERTIES ; LANTHANIDE TRIFLUORIDES ; UP-CONVERSION ; NANOCRYSTALS ; NANOPARTICLES ; POLYMORPHISM ; FLUORIDE ; LITHIUM ; YF3EU3+ ; RAMAN
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000382180000048
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2376351
专题中国科学院大学
通讯作者Zheng, Xianxu; Zhang, Zengming
作者单位1.Univ Sci & Technol China, Dept Phys, Hefei 230026, Anhui, Peoples R China
2.Univ Sci & Technol China, Ctr Phys Expt, Hefei 230026, Anhui, Peoples R China
3.China Acad Engn Phys, Inst Fluid Phys, Mianyang 621900, Sichuan, Peoples R China
4.Univ Sci & Technol China, Key Lab Strongly Coupled Quantum Matter Phys, Chinese Acad Sci, Sch Phys Sci, Hefei 230026, Anhui, Peoples R China
推荐引用方式
GB/T 7714
Sui, Zhilei,Wu, Jizhou,Wang, Xiangqi,et al. Cyclic phase transition from hexagonal to orthorhombic then back to hexagonal of euf3 while loading uniaxial pressure and under high temperature[J]. Journal of physical chemistry c,2016,120(33):18780-18787.
APA Sui, Zhilei.,Wu, Jizhou.,Wang, Xiangqi.,Dai, Rucheng.,Wang, Zhongping.,...&Zhang, Zengming.(2016).Cyclic phase transition from hexagonal to orthorhombic then back to hexagonal of euf3 while loading uniaxial pressure and under high temperature.Journal of physical chemistry c,120(33),18780-18787.
MLA Sui, Zhilei,et al."Cyclic phase transition from hexagonal to orthorhombic then back to hexagonal of euf3 while loading uniaxial pressure and under high temperature".Journal of physical chemistry c 120.33(2016):18780-18787.
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