Cyclic phase transition from hexagonal to orthorhombic then back to hexagonal of euf3 while loading uniaxial pressure and under high temperature | |
Sui, Zhilei1; Wu, Jizhou1; Wang, Xiangqi1; Dai, Rucheng2; Wang, Zhongping2; Zheng, Xianxu3; Zhang, Zengming2,4 | |
刊名 | Journal of physical chemistry c
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2016-08-25 | |
卷号 | 120期号:33页码:18780-18787 |
ISSN号 | 1932-7447 |
DOI | 10.1021/acs.jpcc.6b05907 |
通讯作者 | Zheng, xianxu(zxxgoal109@sina.com) ; Zhang, zengming(zzm@ustc.edu.cn) |
英文摘要 | The structure and photoluminescence properties are investigated under high pressure and high temperature for pure orthorhombic and hexagonal euf3 nanocrystals. under hydrostatic compression, the hexagonal euf3 remains stable at pressures up to 26 gpa. under nonhydrostatic compression, a cyclic phase transition from hexagonal to orthorhombic and then back to hexagonal is observed for the first time. when loading uniaxial compression, the pure hexagonal euf3 partly transforms to orthorhombic at 70 mpa, then the orthorhombic euf3 transforms to hexagonal at about 3 gpa, and the transition is completed at about 10 gpa. the cyclic phase transition is also observed during the heating process; the hexagonal transforms to orthorhombic at 550 degrees c and then to hexagonal at 855 degrees c. the content phase diagrams are obtained under high pressure and at high temperature. |
WOS关键词 | PHOTOLUMINESCENCE PROPERTIES ; LANTHANIDE TRIFLUORIDES ; UP-CONVERSION ; NANOCRYSTALS ; NANOPARTICLES ; POLYMORPHISM ; FLUORIDE ; LITHIUM ; YF3EU3+ ; RAMAN |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS类目 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000382180000048 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2376351 |
专题 | 中国科学院大学 |
通讯作者 | Zheng, Xianxu; Zhang, Zengming |
作者单位 | 1.Univ Sci & Technol China, Dept Phys, Hefei 230026, Anhui, Peoples R China 2.Univ Sci & Technol China, Ctr Phys Expt, Hefei 230026, Anhui, Peoples R China 3.China Acad Engn Phys, Inst Fluid Phys, Mianyang 621900, Sichuan, Peoples R China 4.Univ Sci & Technol China, Key Lab Strongly Coupled Quantum Matter Phys, Chinese Acad Sci, Sch Phys Sci, Hefei 230026, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Sui, Zhilei,Wu, Jizhou,Wang, Xiangqi,et al. Cyclic phase transition from hexagonal to orthorhombic then back to hexagonal of euf3 while loading uniaxial pressure and under high temperature[J]. Journal of physical chemistry c,2016,120(33):18780-18787. |
APA | Sui, Zhilei.,Wu, Jizhou.,Wang, Xiangqi.,Dai, Rucheng.,Wang, Zhongping.,...&Zhang, Zengming.(2016).Cyclic phase transition from hexagonal to orthorhombic then back to hexagonal of euf3 while loading uniaxial pressure and under high temperature.Journal of physical chemistry c,120(33),18780-18787. |
MLA | Sui, Zhilei,et al."Cyclic phase transition from hexagonal to orthorhombic then back to hexagonal of euf3 while loading uniaxial pressure and under high temperature".Journal of physical chemistry c 120.33(2016):18780-18787. |
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