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Impurity-induced formation of bilayered graphene on copper by chemical vapor deposition
Li, Jun1,2; Zhuang, Jianing3; Shen, Chengmin1,4; Tian, Yuan1; Que, Yande1,2; Ma, Ruisong1,2; Pan, Jinbo1,2; Zhang, Yanfang1,2; Wang, Yeliang1,4; Du, Shixuan1,4
刊名Nano research
2016-09-01
卷号9期号:9页码:2803-2810
关键词Graphene Chemical vapor deposition (cvd) Bilayer Growth mechanism
ISSN号1998-0124
DOI10.1007/s12274-016-1169-8
通讯作者Shen, chengmin(cmshen@iphy.ac.cn) ; Ding, feng(feng.ding@polyu.edu.hk) ; Gao, hong-jun(hjgao@iphy.ac.cn)
英文摘要High-quality single-layered and bilayered graphene (slg and blg) was synthesized on copper foil surfaces by controllable chemical vapor deposition (cvd). impurity nanoparticles formed on the copper foil surface by hightemperature annealing were found to play a crucial role in the growth of blg. analysis of energy-dispersive spectrometry (eds) data indicated that these nanoparticles consisted of silicon and aluminum. according to the inverted wedding cake model, these nanoparticles served as nucleation centers for blg growth and the free space between a nanoparticle and graphene served as the center of c injection for the continuous growth of the adlayer beneath the top layer. by combining phase-field theory simulations, we confirmed the mechanism of blg growth and revealed more details about it in comparison with slg growth. for the first time, this study led to a complete understanding of the blg growth mechanism from nucleation to continuous growth in the cvd process, and it has opened a door to the thickness-controllable synthesis of graphene.
WOS关键词GROWTH ; SUBSTRATE
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
语种英语
出版者TSINGHUA UNIV PRESS
WOS记录号WOS:000382882200029
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2376193
专题中国科学院大学
通讯作者Shen, Chengmin; Ding, Feng; Gao, Hong-Jun
作者单位1.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Hong Kong Polytech Univ, Inst Text & Clothing, Kowloon, Hong Kong, Peoples R China
4.Beijing Key Lab Nanomat & Nanodevices, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Li, Jun,Zhuang, Jianing,Shen, Chengmin,et al. Impurity-induced formation of bilayered graphene on copper by chemical vapor deposition[J]. Nano research,2016,9(9):2803-2810.
APA Li, Jun.,Zhuang, Jianing.,Shen, Chengmin.,Tian, Yuan.,Que, Yande.,...&Gao, Hong-Jun.(2016).Impurity-induced formation of bilayered graphene on copper by chemical vapor deposition.Nano research,9(9),2803-2810.
MLA Li, Jun,et al."Impurity-induced formation of bilayered graphene on copper by chemical vapor deposition".Nano research 9.9(2016):2803-2810.
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