Self-powered fluorescence display devices based on a fast self-charging/recharging battery (mg/prussian blue) | |
Zhang, Hui1,2; Yu, You1,2; Zhang, Lingling1,2; Zhai, Yiwen1,2; Dong, Shaojun1,2 | |
刊名 | Chemical science
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2016 | |
卷号 | 7期号:11页码:6721-6727 |
ISSN号 | 2041-6520 |
DOI | 10.1039/c6sc02347a |
通讯作者 | Dong, shaojun(dongsj@ciac.ac.cn) |
英文摘要 | Stimuli-responsive (such as voltage and/or light) fluorescence display systems have attracted particular attention in their promising fields of application. however, there are few examples of self-powered fluorescence display devices. here we designed and fabricated a self-powered fluorescence display device based on a fast-charging/recharging battery. the specially designed battery was composed of a prussian blue (pb) cathode and a magnesium metal anode with a high theoretical redox potential difference (similar to 2.8 v). moreover, smartly adding a trace amount of naclo in the electrolyte could realize oxidizing pw to pb similar to 480 times faster than when oxidizing without naclo, leading to the fast self-charging and high power density (maximum power density of 13.34 mw cm(-2), about two to three orders of magnitude larger than previous bio-fuel cells) of the mg/pb battery. most importantly, pb was used as not only the cathodic catalyst but also as an electrochromic material, making it possible to construct a self-powered and rechargeable electrochromic fluorescence display with only two electrodes. besides, fluorescent [ru(bpy)(3)](2+)-doped silica nanoparticles (ru@ sio2), were selected as the fluorescence resonance energy transfer (fret) donor to match pb (fret acceptor). to the best of our knowledge, we demonstrated a self-powered and rechargeable electrochromic fluorescence display with only two electrodes for the first time. |
WOS关键词 | PRUSSIAN BLUE ; ENERGY-TRANSFER ; PERFORMANCE-CHARACTERISTICS ; COORDINATION POLYMERS ; REVERSIBLE MODULATION ; SILICA NANOPARTICLES ; BIOFUEL CELLS ; ION BATTERY ; ELECTRODES ; NANOWIRES |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000386228900016 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2375011 |
专题 | 中国科学院大学 |
通讯作者 | Dong, Shaojun |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Hui,Yu, You,Zhang, Lingling,et al. Self-powered fluorescence display devices based on a fast self-charging/recharging battery (mg/prussian blue)[J]. Chemical science,2016,7(11):6721-6727. |
APA | Zhang, Hui,Yu, You,Zhang, Lingling,Zhai, Yiwen,&Dong, Shaojun.(2016).Self-powered fluorescence display devices based on a fast self-charging/recharging battery (mg/prussian blue).Chemical science,7(11),6721-6727. |
MLA | Zhang, Hui,et al."Self-powered fluorescence display devices based on a fast self-charging/recharging battery (mg/prussian blue)".Chemical science 7.11(2016):6721-6727. |
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