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	Characterization of ancient korean pigments by surface analytical techniques
	Kim, Minjung1,2; Lee, Jihye1; Doh, Jung-Mann3; Ahn, Heesook4; Kim, Hae Dong2; Yang, Yimin5; Lee, Yeonhee1
刊名	Surface and interface analysis
	2016-07-01
卷号	48期号:7页码:409-414
关键词	Surface analysis Tof-sims Portable xrf Pigments Paintings
ISSN号	0142-2421
DOI	10.1002/sia.5975
通讯作者	Lee, yeonhee(yhlee@kist.re.kr)
英文摘要	The identification of pigments applied in ancient paintings is of great importance for art conservation and history. in this work, pigment samples from the 19th century korean buddhist painting (taenghwa) at the hwangnyongsa temple were analyzed using two analytical techniques: portable x-ray fluorescence (xrf) and time-of-flight secondary ion mass spectrometry (tof-sims). portable xrf was used to obtain elemental information about the pigments applied in the korean guardian buddhist painting. the xrf results revealed the characteristic elements in the pigments that were commonly used in that period. the qualitative and non-destructive xrf analyses of pigment layers of the buddhist painting were compared with results obtained using the micro-destructive tof-sims technique. the tof-sims spectra of the pigments showed characteristic elemental peaks such as pb+, cu+, hg+, al+, and hydrocarbon ions for the white, green, red, blue, and black areas in the positive ion mode and co3-, oh-, s-, cl-, and cnh- in the negative ion mode, respectively. the xrf and tof-sims results show that the white, green, and red areas in the buddhist painting were painted with lead white, malachite, atacamite, cinnabar, and mars red as single or mixed pigments. smalt and carbon were used to depict the blue and black areas in the buddhist painting, respectively. tof-sims combined with complementary methods such as portable xrf provides important information about ancient painting materials on a sub-micrometer scale. therefore, by combining these complementary techniques, a thorough characterization of each pigment can be obtained, allowing for a proper strategy for the restoration process. copyright (c) 2016 john wiley & sons, ltd.
WOS关键词	ION MASS-SPECTROMETRY ; RAMAN-SPECTROSCOPY ; WALL PAINTINGS ; GREEN PIGMENTS ; TOF-SIMS ; IDENTIFICATION ; ARCHAEOLOGY ; ART ; CERAMICS ; XRF
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
语种	英语
出版者	WILEY-BLACKWELL
WOS记录号	WOS:000379680000005
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2374727
专题	中国科学院大学
通讯作者	Lee, Yeonhee
作者单位	1.Korea Inst Sci & Technol, Adv Anal Ctr, Seoul 136791, South Korea 2.Kyung Hee Univ, Dept Chem, Seoul 130701, South Korea 3.Korea Inst Sci & Technol, Interface Control Res Ctr, Seoul 136791, South Korea 4.Dongkook Univ, Dept Buddhist Arts & Culture, Seoul 100715, South Korea 5.Univ Chinese Acad Sci, Dept Sci Hist & Archaeometry, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Kim, Minjung,Lee, Jihye,Doh, Jung-Mann,et al. Characterization of ancient korean pigments by surface analytical techniques[J]. Surface and interface analysis,2016,48(7):409-414.
APA	Kim, Minjung.,Lee, Jihye.,Doh, Jung-Mann.,Ahn, Heesook.,Kim, Hae Dong.,...&Lee, Yeonhee.(2016).Characterization of ancient korean pigments by surface analytical techniques.Surface and interface analysis,48(7),409-414.
MLA	Kim, Minjung,et al."Characterization of ancient korean pigments by surface analytical techniques".Surface and interface analysis 48.7(2016):409-414.

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