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A shape-persistent cryptand for capturing polycyclic aromatic hydrocarbons
Zhang, Rui-Feng1,5; Hu, Wen-Jing1; Liu, Yahu A.2; Zhao, Xiao-Li3,4; Li, Jiu-Sheng1; Jiang, Biao1; Wen, Ke1
刊名Journal of organic chemistry
2016-07-01
卷号81期号:13页码:5649-5654
ISSN号0022-3263
DOI10.1021/acs.joc.6b01115
通讯作者Li, jiu-sheng(lijs@sari.ac.cn) ; Jiang, biao(jiangb@sari.ac.cn) ; Wen, ke(wenk@sari.ac.cn)
英文摘要A shape-persistent cryptand 1, containing two face-to-face oriented electron-deficient 2,4,6-triphenyl-1,3,5-triazine units separated by approximately 7 angstrom, and bridged by two rigid 1,8-naphthyridine linkers and a pentaethylene oxide loop, is created for capturing polycyclic aromatic hydrocarbons. cryptand 1 formed 1:1 complexes with pah guest molecules, such as phenanthrene (6), anthracene (7), pyrene (8), triphenylene (9), and tetraphene (10). the single -crystal structure of complex 6c1 revealed that 6 was included in the cavity of 1 via face-to-face pi center dot center dot center dot pi stacking interactions. soaking crystalline 1 in a toluene solution of anthracene resulted in anthracene from the toluene solution being picked up by the crystalline solid of 1.
WOS关键词LIQUID-CHROMATOGRAPHY ; HOST-GUEST ; SUPRAMOLECULAR POLYMERS ; FORMATION-CONSTANTS ; MOLECULAR TWEEZERS ; BETA-CYCLODEXTRIN ; RECOGNITION ; INCLUSION ; CHEMISTRY ; PAHS
WOS研究方向Chemistry
WOS类目Chemistry, Organic
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000379456500040
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2374628
专题中国科学院大学
通讯作者Li, Jiu-Sheng; Jiang, Biao; Wen, Ke
作者单位1.Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China
2.ChemBridge Res Labs, Med Chem, San Diego, CA 92127 USA
3.East China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
4.East China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China
5.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Rui-Feng,Hu, Wen-Jing,Liu, Yahu A.,et al. A shape-persistent cryptand for capturing polycyclic aromatic hydrocarbons[J]. Journal of organic chemistry,2016,81(13):5649-5654.
APA Zhang, Rui-Feng.,Hu, Wen-Jing.,Liu, Yahu A..,Zhao, Xiao-Li.,Li, Jiu-Sheng.,...&Wen, Ke.(2016).A shape-persistent cryptand for capturing polycyclic aromatic hydrocarbons.Journal of organic chemistry,81(13),5649-5654.
MLA Zhang, Rui-Feng,et al."A shape-persistent cryptand for capturing polycyclic aromatic hydrocarbons".Journal of organic chemistry 81.13(2016):5649-5654.
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