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Effect of fabrication and operating parameters on electrochemical property, of anode and cathode for direct methanol fuel cells
Liu, Guicheng1; Zhou, Hongwei2; Ding, Xianan2; Li, Xinping2; Zou, Dechun3; Li, Xinyang4; Wang, Xindong2; Lee, Joong Kee1
刊名Energy conversion and management
2016-08-15
卷号122页码:366-371
关键词Direct methanol fuel cell Membrane electrode assembly Assembly force Operating parameter Three-electrode system
ISSN号0196-8904
DOI10.1016/j.enconman.2016.06.008
通讯作者Liu, guicheng(log67@163.com) ; Wang, xindong(echem@ustb.edu.cn) ; Lee, joong kee(leejk@kistre.kr)
英文摘要A quick and simple method for optimizing assembly force of the direct methanol fuel cell has been introduced. meanwhile, the effect mechanism of operating parameters on fuel cell performance and the properties of single anode and cathode have been intuitively investigated by a three-electrode system in this paper. the impedance curves indicate that internal resistance is the suitable intermediate to connect assembly torque and assembly force. the cathode polarization curve and limiting current density of methanol crossover are shown that the increasing methanol concentration markedly exacerbates the polarization in cathode due to serious methanol crossover phenomenon. also, the higher cathode back pressure mainly improves cathode property, and lowers methanol crossover simultaneously. finally, the summaries of peak power densities prove that the main factor that affected the optimal flow rates of methanol and oxygen is not the concentration or backpressure, but the working temperature, (c) 2016 elsevier ltd. all rights reserved.
WOS关键词CLAMPING PRESSURE ; ASSEMBLY PRESSURE ; CATALYST LAYER ; PERFORMANCE ; MEMBRANE ; STACK ; STABILITY ; OXYGEN
WOS研究方向Thermodynamics ; Energy & Fuels ; Mechanics ; Physics
WOS类目Thermodynamics ; Energy & Fuels ; Mechanics ; Physics, Nuclear
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000379632600034
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2374609
专题中国科学院大学
通讯作者Liu, Guicheng; Wang, Xindong; Lee, Joong Kee
作者单位1.Korea Inst Sci & Technol, Green City Res Inst, Ctr Energy Convergence Res, Hwarang Ro 14 Gil 5, Seoul 02792, South Korea
2.Univ Sci & Technol Beijing, Dept Phys Chem, 30 Xueyuan Rd, Beijing 100083, Peoples R China
3.Peking Univ, Coll Chem & Mol Engn, Minist Educ, Beijing Natl Lab Mol Sci,Key Lab Polymer Chem & P, Beijing 100871, Peoples R China
4.Univ Chinese Acad Sci, Coll Resources & Environm, Beijing 100049, Peoples R China
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GB/T 7714
Liu, Guicheng,Zhou, Hongwei,Ding, Xianan,et al. Effect of fabrication and operating parameters on electrochemical property, of anode and cathode for direct methanol fuel cells[J]. Energy conversion and management,2016,122:366-371.
APA Liu, Guicheng.,Zhou, Hongwei.,Ding, Xianan.,Li, Xinping.,Zou, Dechun.,...&Lee, Joong Kee.(2016).Effect of fabrication and operating parameters on electrochemical property, of anode and cathode for direct methanol fuel cells.Energy conversion and management,122,366-371.
MLA Liu, Guicheng,et al."Effect of fabrication and operating parameters on electrochemical property, of anode and cathode for direct methanol fuel cells".Energy conversion and management 122(2016):366-371.
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