Effect of fabrication and operating parameters on electrochemical property, of anode and cathode for direct methanol fuel cells | |
Liu, Guicheng1; Zhou, Hongwei2; Ding, Xianan2; Li, Xinping2; Zou, Dechun3; Li, Xinyang4; Wang, Xindong2; Lee, Joong Kee1 | |
刊名 | Energy conversion and management |
2016-08-15 | |
卷号 | 122页码:366-371 |
关键词 | Direct methanol fuel cell Membrane electrode assembly Assembly force Operating parameter Three-electrode system |
ISSN号 | 0196-8904 |
DOI | 10.1016/j.enconman.2016.06.008 |
通讯作者 | Liu, guicheng(log67@163.com) ; Wang, xindong(echem@ustb.edu.cn) ; Lee, joong kee(leejk@kistre.kr) |
英文摘要 | A quick and simple method for optimizing assembly force of the direct methanol fuel cell has been introduced. meanwhile, the effect mechanism of operating parameters on fuel cell performance and the properties of single anode and cathode have been intuitively investigated by a three-electrode system in this paper. the impedance curves indicate that internal resistance is the suitable intermediate to connect assembly torque and assembly force. the cathode polarization curve and limiting current density of methanol crossover are shown that the increasing methanol concentration markedly exacerbates the polarization in cathode due to serious methanol crossover phenomenon. also, the higher cathode back pressure mainly improves cathode property, and lowers methanol crossover simultaneously. finally, the summaries of peak power densities prove that the main factor that affected the optimal flow rates of methanol and oxygen is not the concentration or backpressure, but the working temperature, (c) 2016 elsevier ltd. all rights reserved. |
WOS关键词 | CLAMPING PRESSURE ; ASSEMBLY PRESSURE ; CATALYST LAYER ; PERFORMANCE ; MEMBRANE ; STACK ; STABILITY ; OXYGEN |
WOS研究方向 | Thermodynamics ; Energy & Fuels ; Mechanics ; Physics |
WOS类目 | Thermodynamics ; Energy & Fuels ; Mechanics ; Physics, Nuclear |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000379632600034 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2374609 |
专题 | 中国科学院大学 |
通讯作者 | Liu, Guicheng; Wang, Xindong; Lee, Joong Kee |
作者单位 | 1.Korea Inst Sci & Technol, Green City Res Inst, Ctr Energy Convergence Res, Hwarang Ro 14 Gil 5, Seoul 02792, South Korea 2.Univ Sci & Technol Beijing, Dept Phys Chem, 30 Xueyuan Rd, Beijing 100083, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, Minist Educ, Beijing Natl Lab Mol Sci,Key Lab Polymer Chem & P, Beijing 100871, Peoples R China 4.Univ Chinese Acad Sci, Coll Resources & Environm, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Guicheng,Zhou, Hongwei,Ding, Xianan,et al. Effect of fabrication and operating parameters on electrochemical property, of anode and cathode for direct methanol fuel cells[J]. Energy conversion and management,2016,122:366-371. |
APA | Liu, Guicheng.,Zhou, Hongwei.,Ding, Xianan.,Li, Xinping.,Zou, Dechun.,...&Lee, Joong Kee.(2016).Effect of fabrication and operating parameters on electrochemical property, of anode and cathode for direct methanol fuel cells.Energy conversion and management,122,366-371. |
MLA | Liu, Guicheng,et al."Effect of fabrication and operating parameters on electrochemical property, of anode and cathode for direct methanol fuel cells".Energy conversion and management 122(2016):366-371. |
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