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Facile synthesis of gamma-mnooh nanorods via a redox precipitation route using oxygen and their thermal conversion
Zhang, Lei1,2; Wang, Sheng1; Ding, Ya1,2; Lv, Li-Rong1,2; Chen, Ya-Tu1,2; Xu, De-Kang1,2; Wang, Shu-Dong1
刊名Chemistryselect
2018-11-15
卷号3期号:42页码:11908-11913
关键词Green synthesis Manganese oxohydroxide Nanorods
ISSN号2365-6549
DOI10.1002/slct.201803315
通讯作者Wang, sheng(wangsheng@dicp.ac.cn) ; Wang, shu-dong(wangsd@dicp.ac.cn)
英文摘要A green chemistry approach was successfully fabricated in this work to synthesize gamma-mnooh nanorods under mild conditions, in which oxygen was used as the green oxidizer and no surfactants or templates were involved. only the oxygen was bubbled through the solutions of divalent manganese in the presence of naoh. the morpholgy and structure of gamma-mnooh were dependent on several cruicial factors, i. e. the amount of glacial acetic acid (hac), the kind of anions, reaction time, and reaction temperature. to gain mechanistic information on the dependence, the gamma-mnooh nanorods were characterized by tem, sem and xrd. results showed that gamma-mnooh nanorods were evolved from mn3o4 by a redox process. furthermore, the corresponding beta-mno2, alpha-mn2o3, mn3o4 were prepared by calcining gamma-mnooh nanorods under different temperature and atmosphere. among them, beta-mno2 nanorods were most efficient for the catalytic decomposition of o-3.
WOS关键词MANGANESE OXIDE NANOSTRUCTURES ; NANOPARTICLES ; PERFORMANCE ; OXIDATION ; BETA-MNO2
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000450365000029
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2373032
专题大连化学物理研究所
通讯作者Wang, Sheng; Wang, Shu-Dong
作者单位1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Lei,Wang, Sheng,Ding, Ya,et al. Facile synthesis of gamma-mnooh nanorods via a redox precipitation route using oxygen and their thermal conversion[J]. Chemistryselect,2018,3(42):11908-11913.
APA Zhang, Lei.,Wang, Sheng.,Ding, Ya.,Lv, Li-Rong.,Chen, Ya-Tu.,...&Wang, Shu-Dong.(2018).Facile synthesis of gamma-mnooh nanorods via a redox precipitation route using oxygen and their thermal conversion.Chemistryselect,3(42),11908-11913.
MLA Zhang, Lei,et al."Facile synthesis of gamma-mnooh nanorods via a redox precipitation route using oxygen and their thermal conversion".Chemistryselect 3.42(2018):11908-11913.
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