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	Synthesis of jet fuel additive with cyclopentanone
	Tang, Hao1,2; Chen, Fang1,2; Li, Guangyi1; Yang, Xiaofeng1; Hu, Yancheng1; Wang, Aiqin1,3; Cong, Yu1; Wang, Xiaodong1; Zhang, Tao1,3; Li, Ning1,3
刊名	Journal of energy chemistry
	2019-02-01
卷号	29页码:23-30
关键词	Lignocellulose Jet fuel additive Aldol condensation Dehydration/rearrangement Hydrogenation
ISSN号	2095-4956
DOI	10.1016/j.jechem.2018.01.017
通讯作者	Li, ning(lining@dicp.ac.cn)
英文摘要	A new route was developed for the synthesis of renewable decalin with cyclopentanone which can be derived from lignocellulose. it was found that 1,2,3,4,5,6,7,8-octahydronaphthalene could be selectively produced by the hydrogenation/dehydration/rearrangement of [1,1'-bi(cyclopentylidene)]-2-one (i.e. the self-aldol condensation product of cyclopentanone) over a dual-bed catalyst system. among the investigated catalysts, the ru/c and amberlyst-15 resin exhibited the highest activities for the hydrogenation of [1,1'-bi(cyclopentylidene)]-2-one to [1,1'-bi(cyclopentan)]-2-ol and the dehydration/rearrangement of [1,1'-bi(cyclopentan)]-2-ol to 1,2,3,4,5,6,7,8-octahydronaphthalene, respectively. using ru/c and amberlyst-15 resin as the first bed and the second bed catalysts, 1,2,3,4,5,6,7,8-octahydronaphthalene was directly produced in high carbon yield (83.7%) under mild conditions (393 k, 1 mpa). after being hydrogenated, the 1,2,3,4,5,6,7,8-octahydronaphthalene was converted to decalin which can be used as additive to improve the thermal stability and volumetric heat value of jet fuel. (c) 2018 science press and dalian institute of chemical physics, chinese academy of sciences. published by elsevier by, and science press. all rights reserved.
WOS关键词	DENSITY AVIATION FUEL ; POT CATALYTIC CONVERSION ; MULTIFUNCTIONAL CATALYST ; SELECTIVE HYDROGENATION ; NANOPARTICLE CATALYSTS ; AROMATIC-HYDROCARBONS ; GAMMA-VALEROLACTONE ; LIQUID ALKANES ; WOODY BIOMASS ; HYDRODEOXYGENATION
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000451732100005
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2372978
专题	大连化学物理研究所
通讯作者	Li, Ning
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM Collaborat Innovat Ctr Chem Energy Mat, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Tang, Hao,Chen, Fang,Li, Guangyi,et al. Synthesis of jet fuel additive with cyclopentanone[J]. Journal of energy chemistry,2019,29:23-30.
APA	Tang, Hao.,Chen, Fang.,Li, Guangyi.,Yang, Xiaofeng.,Hu, Yancheng.,...&Li, Ning.(2019).Synthesis of jet fuel additive with cyclopentanone.Journal of energy chemistry,29,23-30.
MLA	Tang, Hao,et al."Synthesis of jet fuel additive with cyclopentanone".Journal of energy chemistry 29(2019):23-30.

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