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	Synthesis of spiropyrrolidine oxindoles through rh(ii)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides
	Yi, Ruxia1,2; Qian, Leilei1,2; Wan, Boshun1
刊名	Chinese journal of catalysis
	2019-02-01
卷号	40期号:2页码:177-183
关键词	Rhodium catalyst Vinyl azides Diazo compounds Spiropyrrolidine oxindoles Olefination [1+1+3] annulation
ISSN号	0253-9837
DOI	10.1016/s1872-2067(18)63200-0
通讯作者	Wan, boshun(bswan@dicp.ac.cn)
英文摘要	A simple and efficient process involving the rh(ii)-catalyzed [1+1+3] annulation of diazooxindoles and vinyl azides has been developed for the synthesis of spiropyrrolidine oxindoles with potential biological activity and significant synthetic applications. this process involves a novel rhodium-catalyzed olefination of diazo compounds, followed by annulation with vinyl azides. this method is compatible with a broad range of substrates and affords moderate to good yields under mild reaction conditions. (c) 2019, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved.
WOS关键词	MICHAEL ADDITION/CYCLIZATION ; ENANTIOSELECTIVE SYNTHESIS ; EFFICIENT SYNTHESIS ; INDOLE ALKALOIDS ; CONSTRUCTION ; CYCLOADDITION ; ISATIN ; KETIMINES ; CASCADE
WOS研究方向	Chemistry ; Engineering
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000457815900006
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2372844
专题	大连化学物理研究所
通讯作者	Wan, Boshun
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yi, Ruxia,Qian, Leilei,Wan, Boshun. Synthesis of spiropyrrolidine oxindoles through rh(ii)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides[J]. Chinese journal of catalysis,2019,40(2):177-183.
APA	Yi, Ruxia,Qian, Leilei,&Wan, Boshun.(2019).Synthesis of spiropyrrolidine oxindoles through rh(ii)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides.Chinese journal of catalysis,40(2),177-183.
MLA	Yi, Ruxia,et al."Synthesis of spiropyrrolidine oxindoles through rh(ii)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides".Chinese journal of catalysis 40.2(2019):177-183.

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