| Production of 1,2-cyclohexanedicarboxylates from diacetone alcohol and fumarates | |
| Hu, Yancheng1; Yuan, Lin1,2; Zhang, Xiuli1,3; Zhou, Han1,3; Wang, Pan1,3; Li, Guangyi1; Wang, Aiqin1; Cong, Yu1; Zhang, Tao1; Liang, Xinmiao1,3 | |
| 刊名 | Acs sustainable chemistry & engineering
 |
| 2019-02-04 | |
| 卷号 | 7期号:3页码:2980-2988 |
| 关键词 | Plasticizers Diacetone alcohol Fumarates Dehydration/diels-alder reaction Hydrogenation 1,2-cyclohexanedicarboxylate |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.8b04310 |
| 通讯作者 | Li, wei(liwei820927@nefu.edu.cn) ; Li, ning(lining@dicp.ac.cn) |
| 英文摘要 | 1,2-cyclohexanedicarboxylates, which are one of the most commonly used plasticizers in the poly(vinyl chloride) (pvc) industry, are generally prepared via the oxidation/esterification/hydrogenation of o-xylene (or naphthalene). herein, we develop an alternative route toward cyclohexane-based plasticizers using diacetone alcohol and fumarates as the starting materials. the process includes a mild raney ni-catalyzed hydrogenation of diacetone alcohol, an one-step dehydration/diels-alder reaction of resulting 2-methyl-2,4-pentandiol and fumarates in a choline chloride (chcl) based deep eutectic solvent (des), and a further pd/c-catalyzed hydrogenation. the toxicological tests indicate that the as-synthesized di(2-ethylhexyl) 3,5-dimethylcyclohexane-1,2-dicarboxylate can serve as a safe plasticizer for pvc materials. |
| WOS关键词 | SUSTAINABLE PRODUCTION ; CATALYTIC CONVERSION ; PLATFORM CHEMICALS ; MALEIC-ANHYDRIDE ; ETHYLENE-GLYCOL ; BIOMASS ; ACID ; PINACOL ; FUELS ; CONDENSATION |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| WOS类目 | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000458086100015 |
| 内容类型 | 期刊论文 |
| URI标识 | http://www.corc.org.cn/handle/1471x/2372802 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Li, Wei; Li, Ning |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Key Lab Separat Sci Analyt Chem, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 4.Northeast Forestry Univ, Key Lab Biobased Mat Sci & Technol, Minist Educ, Hexing Rd 26, Harbin 150040, Heilongjiang, Peoples R China 5.Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Yancheng,Yuan, Lin,Zhang, Xiuli,et al. Production of 1,2-cyclohexanedicarboxylates from diacetone alcohol and fumarates[J]. Acs sustainable chemistry & engineering,2019,7(3):2980-2988. |
| APA | Hu, Yancheng.,Yuan, Lin.,Zhang, Xiuli.,Zhou, Han.,Wang, Pan.,...&Li, Ning.(2019).Production of 1,2-cyclohexanedicarboxylates from diacetone alcohol and fumarates.Acs sustainable chemistry & engineering,7(3),2980-2988. |
| MLA | Hu, Yancheng,et al."Production of 1,2-cyclohexanedicarboxylates from diacetone alcohol and fumarates".Acs sustainable chemistry & engineering 7.3(2019):2980-2988. |
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