In Situ Raman Spectral Characteristics of Carbon Dioxide in a Deep-Sea Simulator of Extreme Environments Reaching 300? and 30MPa

doi:10.1177/0003702817722820

CORC > 海洋研究所 > 中国科学院海洋研究所 > 海洋地质与环境重点实验室

	In Situ Raman Spectral Characteristics of Carbon Dioxide in a Deep-Sea Simulator of Extreme Environments Reaching 300? and 30MPa
	Li, Lianfu 1,2,3,4; Du, Zengfeng 1,3; Zhang, Xin 1,2,3; Xi, Shichuan 1,4; Wang, Bing 1,4; Luan, Zhendong 1,3; Lian, Chao 3; Yan, Jun 1
刊名	APPLIED SPECTROSCOPY
	2018
卷号	72 期号:1 页码:48-59
关键词	Carbon Dioxide Co2 Laser Raman In Situ Hydrothermal Vent Cold Seep
DOI	10.1177/0003702817722820
文献子类	Article
英文摘要	Deep-sea carbon dioxide (CO2) plays a significant role in the global carbon cycle and directly affects the living environment of marine organisms. In situ Raman detection technology is an effective approach to study the behavior of deep-sea CO2. However, the Raman spectral characteristics of CO2 can be affected by the environment, thus restricting the phase identification and quantitative analysis of CO2. In order to study the Raman spectral characteristics of CO2 in extreme environments (up to 300? and 30MPa), which cover most regions of hydrothermal vents and cold seeps around the world, a deep-sea extreme environment simulator was developed. The Raman spectra of CO2 in different phases were obtained with Raman insertion probe (RiP) system, which was also used in in situ Raman detection in the deep sea carried by remotely operated vehicle (ROV) Faxian. The Raman frequency shifts and bandwidths of gaseous, liquid, solid, and supercritical CO2 and the CO2-H2O system were determined with the simulator. In our experiments (0-300? and 0-30MPa), the peak positions of the symmetric stretching modes of gaseous CO2, liquid CO2, and supercritical CO2 shift approximately 0.6cm(-1) (1387.8-1388.4cm(-1)), 0.7cm(-1) (1385.5-1386.2cm(-1)), and 2.5cm(-1) (1385.7-1388.2cm(-1)), and those of the bending modes shift about 1.0cm(-1) (1284.7-1285.7cm(-1)), 1.9cm(-1) (1280.1-1282.0cm(-1)), and 4.4cm(-1) (1281.0-1285.4cm(-1)), respectively. The Raman spectral characteristics of the CO2-H2O system were also studied under the same conditions. The peak positions of dissolved CO2 varied approximately 4.5cm(-1) (1282.5-1287.0cm(-1)) and 2.4cm(-1) (1274.4-1276.8cm(-1)) for each peak. In comparison with our experiment results, the phases of CO2 in extreme conditions (0-3000m and 0-300?) can be identified with the Raman spectra collected in situ. This qualitative research on CO2 can also support the further quantitative analysis of dissolved CO2 in extreme conditions.
语种	英语
WOS记录号	WOS:000418952400004
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.qdio.ac.cn/handle/337002/154307]
专题	海洋研究所_海洋地质与环境重点实验室
作者单位	1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Geol & Environm, Qingdao 266071, Peoples R China 2.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Geol, Qingdao, Peoples R China 3.Chinese Acad Sci, Inst Oceanol, Deep Sea Res Ctr, Qingdao, Peoples R China 4.Univ Chinese Acad Sci, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Li, Lianfu,Du, Zengfeng,Zhang, Xin,et al. In Situ Raman Spectral Characteristics of Carbon Dioxide in a Deep-Sea Simulator of Extreme Environments Reaching 300? and 30MPa[J]. APPLIED SPECTROSCOPY,2018,72(1):48-59.
APA	Li, Lianfu.,Du, Zengfeng.,Zhang, Xin.,Xi, Shichuan.,Wang, Bing.,...&Yan, Jun.(2018).In Situ Raman Spectral Characteristics of Carbon Dioxide in a Deep-Sea Simulator of Extreme Environments Reaching 300? and 30MPa.APPLIED SPECTROSCOPY,72(1),48-59.
MLA	Li, Lianfu,et al."In Situ Raman Spectral Characteristics of Carbon Dioxide in a Deep-Sea Simulator of Extreme Environments Reaching 300? and 30MPa".APPLIED SPECTROSCOPY 72.1(2018):48-59.