Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates

CORC > 昆明植物研究所 > 中国科学院昆明植物研究所 > 植物化学与西部植物资源持续利用国家重点实验室

	Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates
	Zheng, Yu 1,2; Yue, Bei-Bei 1,2; Wei, Kun 1; Yang, Yu-Rong1
刊名	ORGANIC LETTERS
	2018-12-21
卷号	20 期号:24 页码:8035-8038
ISSN号	1523-7060
英文摘要	Carreira's iridium-(P, olefin) phosphoramidite-based catalytic system that allows asymmetric allyl-allylboronate cross-coupling with high enantioselectivity is reported. This transformation tolerates a large variety of racemic branched allylic alcohols and allylboronate substrates. The utility of the coupling is demonstrated in a concise catalytic asymmetric synthesis of (-)-preclamol.
资助项目	Key Research Program of the Frontier Sciences of the CAS[QYZDB-SSW-SMC026] ; NSFC[21672224] ; NSFC[21472200] ; Government of Yunnan Province[2017FA002]
语种	英语
资助机构	Key Research Program of the Frontier Sciences of the CAS ; NSFC ; Government of Yunnan Province
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn/handle/151853/64370]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
通讯作者	Yang, Yu-Rong
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zheng, Yu,Yue, Bei-Bei,Wei, Kun,et al. Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates[J]. ORGANIC LETTERS,2018,20(24):8035-8038.
APA	Zheng, Yu,Yue, Bei-Bei,Wei, Kun,&Yang, Yu-Rong.(2018).Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates.ORGANIC LETTERS,20(24),8035-8038.
MLA	Zheng, Yu,et al."Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates".ORGANIC LETTERS 20.24(2018):8035-8038.