Rh(II) carbene S-H insertion into H2S via the stepwise mechanism

	Rh(II) carbene S-H insertion into H2S via the stepwise mechanism
	Liu, Zhen Feng; Yue, Xian Fang; Wei, Qiang; Han, Ke Li
刊名	chinese chemical letters
	2007
卷号	18 期号:1 页码:107-110
关键词	sulfonium ylides 1 density functional calculations dirhodium(II) carbene 2-hydrogen shift
通讯作者	韩克利
产权排序	1;1
英文摘要	the mechanism of rh(h) carbene s-h insertion into h2s in gas phase has been studied by b3lyp functional. calculation results showed that the rh(ii) carbene s-h insertion into h2s took only stepwise channels and no concerted channels had been located, which was different from the rh(h) carbene c-h and o-h insertions. (c) 2006 ke li han. published by elsevier b.v. on behalf of chinese chemical society. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	diazo compound ; tetracarboxylate ; cyclopropenation ; aldehydes ; density ; alkynes
收录类别	SCI
原文出处	true
语种	英语
WOS记录号	WOS:000244443600033
公开日期	2010-11-30
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/98533]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Liu, Zhen Feng,Yue, Xian Fang,Wei, Qiang,et al. Rh(II) carbene S-H insertion into H2S via the stepwise mechanism[J]. chinese chemical letters,2007,18(1):107-110.
APA	Liu, Zhen Feng,Yue, Xian Fang,Wei, Qiang,&Han, Ke Li.(2007).Rh(II) carbene S-H insertion into H2S via the stepwise mechanism.chinese chemical letters,18(1),107-110.
MLA	Liu, Zhen Feng,et al."Rh(II) carbene S-H insertion into H2S via the stepwise mechanism".chinese chemical letters 18.1(2007):107-110.