The oxygen activated by the active vanadium species for the selective oxidation of benzene to phenol

	The oxygen activated by the active vanadium species for the selective oxidation of benzene to phenol
	Gao, Xiaohan; Xu, Jie
刊名	catalysis letters
	2006-11-01
卷号	111 期号:3-4 页码:203-205
关键词	activation of oxygen active vanadium species selective oxidation benzene phenol
通讯作者	徐杰
产权排序	1;1
英文摘要	the activation of oxygen is a key step for the selective oxidation of benzene to phenol and the reason is discussed. the active oxygen species is produced from molecular oxygen in a so-called "reductive activation" process. the vanadium oxide supported on alumina was pre-reduced by hydrogen or ascorbic acid to lower valence vanadium species acting as reduction source and the activity is investigated in the reaction. it is found that the v4+ valence vanadium (vo2+) is effective for the reaction from the characterization of catalysts by xps.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	liquid-phase oxidation ; x-ray electron ; hydrogen-peroxide ; spectroscopy ; catalysts ; oxides ; zeolites ; hydroxylation ; iron
收录类别	SCI
原文出处	true
语种	英语
WOS记录号	WOS:000241578200015
公开日期	2010-11-30
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/97865]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Gao, Xiaohan,Xu, Jie. The oxygen activated by the active vanadium species for the selective oxidation of benzene to phenol[J]. catalysis letters,2006,111(3-4):203-205.
APA	Gao, Xiaohan,&Xu, Jie.(2006).The oxygen activated by the active vanadium species for the selective oxidation of benzene to phenol.catalysis letters,111(3-4),203-205.
MLA	Gao, Xiaohan,et al."The oxygen activated by the active vanadium species for the selective oxidation of benzene to phenol".catalysis letters 111.3-4(2006):203-205.