CO adsorption on highly dispersed MoP/Al2O3 prepared with citric acid | |
Cheng, Ruihua; Shu, Yuying; Li, Lin; Sun, Jun; Wang, Xiaodong; Zhang, Tao | |
刊名 | thermochimica acta |
2006-11-15 | |
卷号 | 450期号:1-2页码:42-46 |
关键词 | calorimetry FT-IR CO adsorption alumina-supported molybdenum phosphide citric acid |
通讯作者 | 张涛 |
产权排序 | 1;1 |
英文摘要 | calorimetry of co adsorption was used for the first time to study the surface properties of alumina-supported molybdenum phosphide (mop/al2o3). to increase the dispersion of mop active sites, the sample was prepared by novel citric acid-temperature programmed reduction (ca-tpr) method. fourier transform infrared spectroscopy (ft-ir) of co adsorption confirmed the formation of mop by ca-tpr method. the calorimetry results proved that the novel method increased the amounts of active sites and led to the formation of a highly dispersed alumina-supported mop, but the adsorption heat and the active sites distribution were not much affected by the preparation method. furthermore, the energetic distribution of active sites depended on the mop loading. (c) 2006 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, analytical ; chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | molybdenum nitride catalysts ; h-2 adsorption ; phosphide ; microcalorimetry ; alumina |
收录类别 | ISTP ; SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000242290300009 |
公开日期 | 2010-11-30 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/97695] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Cheng, Ruihua,Shu, Yuying,Li, Lin,et al. CO adsorption on highly dispersed MoP/Al2O3 prepared with citric acid[J]. thermochimica acta,2006,450(1-2):42-46. |
APA | Cheng, Ruihua,Shu, Yuying,Li, Lin,Sun, Jun,Wang, Xiaodong,&Zhang, Tao.(2006).CO adsorption on highly dispersed MoP/Al2O3 prepared with citric acid.thermochimica acta,450(1-2),42-46. |
MLA | Cheng, Ruihua,et al."CO adsorption on highly dispersed MoP/Al2O3 prepared with citric acid".thermochimica acta 450.1-2(2006):42-46. |
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