CO adsorption on highly dispersed MoP/Al2O3 prepared with citric acid
Cheng, Ruihua; Shu, Yuying; Li, Lin; Sun, Jun; Wang, Xiaodong; Zhang, Tao
刊名thermochimica acta
2006-11-15
卷号450期号:1-2页码:42-46
关键词calorimetry FT-IR CO adsorption alumina-supported molybdenum phosphide citric acid
通讯作者张涛
产权排序1;1
英文摘要calorimetry of co adsorption was used for the first time to study the surface properties of alumina-supported molybdenum phosphide (mop/al2o3). to increase the dispersion of mop active sites, the sample was prepared by novel citric acid-temperature programmed reduction (ca-tpr) method. fourier transform infrared spectroscopy (ft-ir) of co adsorption confirmed the formation of mop by ca-tpr method. the calorimetry results proved that the novel method increased the amounts of active sites and led to the formation of a highly dispersed alumina-supported mop, but the adsorption heat and the active sites distribution were not much affected by the preparation method. furthermore, the energetic distribution of active sites depended on the mop loading. (c) 2006 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, analytical ; chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]molybdenum nitride catalysts ; h-2 adsorption ; phosphide ; microcalorimetry ; alumina
收录类别ISTP ; SCI
原文出处true
语种英语
WOS记录号WOS:000242290300009
公开日期2010-11-30
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/97695]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Cheng, Ruihua,Shu, Yuying,Li, Lin,et al. CO adsorption on highly dispersed MoP/Al2O3 prepared with citric acid[J]. thermochimica acta,2006,450(1-2):42-46.
APA Cheng, Ruihua,Shu, Yuying,Li, Lin,Sun, Jun,Wang, Xiaodong,&Zhang, Tao.(2006).CO adsorption on highly dispersed MoP/Al2O3 prepared with citric acid.thermochimica acta,450(1-2),42-46.
MLA Cheng, Ruihua,et al."CO adsorption on highly dispersed MoP/Al2O3 prepared with citric acid".thermochimica acta 450.1-2(2006):42-46.
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