Hydrogen evolution based on the electrons/protons stored on amorphous TiO2 | |
Zeng, Shuwen1; Zhang, Ling; Wang, Wenzhong; Shao, Dengkui1; Hao, Hongchang1 | |
刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS |
2017 | |
卷号 | 19期号:43页码:29053 |
ISSN号 | 1463-9076 |
DOI | 10.1039/c7cp06067j |
英文摘要 | The hydrogen evolution reaction (HER) using recyclable mediator is being actively pursued as a route for solar energy conversion. Herein, we introduce a catalyst mediator (MoS2) that enables proton-coupled electron transfer (PCET) process on the recyclable TiO2 (H+-TiO2/e(-)) to a separate, catalytic hydrogen production step without requiring post-light energy input. This approach supplies a new insight to hydrogen evolution with the recyclable proton-electron pairs, stored at the semiconductor after the light irradiation. It was found that 80% of the electrons stored on TiO2 could be devoted to the reduction of H+ into H-2 on MoS2 nanosheets in the dark. The electron transfer to MoS2 occurs at a rate of 455 lmol h(-1) g(-1) and 947 lmol h(-1) g(-1) in the dark and excited state, respectively. |
WOS记录号 | WOS:000414773100003 |
内容类型 | 期刊论文 |
源URL | [http://ir.sic.ac.cn/handle/331005/26628] |
专题 | 中国科学院上海硅酸盐研究所 |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, 1295 Dingxi Rd, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zeng, Shuwen,Zhang, Ling,Wang, Wenzhong,et al. Hydrogen evolution based on the electrons/protons stored on amorphous TiO2[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2017,19(43):29053. |
APA | Zeng, Shuwen,Zhang, Ling,Wang, Wenzhong,Shao, Dengkui,&Hao, Hongchang.(2017).Hydrogen evolution based on the electrons/protons stored on amorphous TiO2.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,19(43),29053. |
MLA | Zeng, Shuwen,et al."Hydrogen evolution based on the electrons/protons stored on amorphous TiO2".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 19.43(2017):29053. |
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