Covalent combination of polyoxometalate and graphitic carbon nitride for light-driven hydrogen peroxide production

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 中国科学院饮用水科学与技术重点实验室

	Covalent combination of polyoxometalate and graphitic carbon nitride for light-driven hydrogen peroxide production
	Zhao, Xu; Zhang, Hui; Zhu, Yongfa; Li, Jiang; Zhao, Shen
刊名	NANO ENERGY
	2017-05-01
卷号	35 期号:0 页码:405-414
关键词	Graphitic Carbon Nitride Polyoxometalates Covalent Combination Hydrogen Peroxide Production
英文摘要	The polyoxometalate (POM) cluster of [PW11O39](7-) (PW11) has been successfully covalent combined with the three dimensionally ordered macroporous graphitic carbon nitride (3DOM g-C3N4) through the organic linker strategy. The characterization such as solid-state NMR and XPS results confirm the organosilicon agent of (triethoxysilyl)-propyl isocyanate can act as the linker to covalent combine the PW11 cluster with 3DOM g-C3N4. The hybrid catalyst of 3DOM g-C3N4-PW11 exhibits efficient catalytic performance (2.4 mu mol h(-1)) for light-driven H2O2 production from H2O and O-2 in the absence of organic electron donors. The ESR results suggest that one-electron reduction of O-2 to center dot OOH is indeed suppressed over 3DOM g-C3N4-PW11. Furthermore, the Koutecky-Levich plot obtained from electrochemical rotating disk electrode (RDE) analysis of oxygen reduction reaction (ORR) for 3DOM g-C3N4-PW11 reveals the value of electron transfer during the ORR process is 2.30, indicating the covalent combination can promote the two-electron O-2 reduction. In addition, the recycle experiment results reveal that the heterogeneous 3DOM g-C3N4-PW11 is catalytic stable.
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/39680]
专题	生态环境研究中心_中国科学院饮用水科学与技术重点实验室
推荐引用方式 GB/T 7714	Zhao, Xu,Zhang, Hui,Zhu, Yongfa,et al. Covalent combination of polyoxometalate and graphitic carbon nitride for light-driven hydrogen peroxide production[J]. NANO ENERGY,2017,35(0):405-414.
APA	Zhao, Xu,Zhang, Hui,Zhu, Yongfa,Li, Jiang,&Zhao, Shen.(2017).Covalent combination of polyoxometalate and graphitic carbon nitride for light-driven hydrogen peroxide production.NANO ENERGY,35(0),405-414.
MLA	Zhao, Xu,et al."Covalent combination of polyoxometalate and graphitic carbon nitride for light-driven hydrogen peroxide production".NANO ENERGY 35.0(2017):405-414.