Synthesis and glycosyllation of pyrimidin-2-yl 1-thio-alpha-D-manno- and -alpha-L-rhamnopyranoside

doi:10.1016/S0008-6215(98)00164-5

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 中国科学院环境生物技术重点实验室

	Synthesis and glycosyllation of pyrimidin-2-yl 1-thio-alpha-D-manno- and -alpha-L-rhamnopyranoside
	Ding, XL; Yang, GB; Kong, FZ
刊名	CARBOHYDRATE RESEARCH
	1998
卷号	310 期号:2015-01-02 页码:135-139
关键词	Pyrimidin-2-yl 1-thio-alpha-d-mannopyranoside 1-thio-alpha-l-rhamnopyranoside
DOI	10.1016/S0008-6215(98)00164-5
英文摘要	Pyrimidin-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-alpha-D-mannopyrano side (9), pyrimidin-2-yl 2,3,4-tri-O-benzyl-alpha-L-rhamnopyranoside (10), pyrimidin-2-yl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-alpha-D-mannopyranoside (7), and pyrimidin-2-y1 2-O-acetyl-3,4-di-O-benzyl-1-thio-alpha-L-rhamnopyranoside (8) were prepared almost quantitatively fi om the corresponding protected 1,2-O-methoxyethylidene-beta-D-manno-or-beta-L-rhamnopyranose with 2-mercaptopyrimidine in the presence of mercuric bromide. Coupling reactions of the thioglycosides promoted by silver triflate with suitable glycosyl accepters afforded 1,2-trans linked disaccharides. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.
WOS研究方向	Biochemistry & Molecular Biology ; Chemistry
WOS记录号	WOS:000076439100017
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/24297]
专题	生态环境研究中心_中国科学院环境生物技术重点实验室
推荐引用方式 GB/T 7714	Ding, XL,Yang, GB,Kong, FZ. Synthesis and glycosyllation of pyrimidin-2-yl 1-thio-alpha-D-manno- and -alpha-L-rhamnopyranoside[J]. CARBOHYDRATE RESEARCH,1998,310(2015-01-02):135-139.
APA	Ding, XL,Yang, GB,&Kong, FZ.(1998).Synthesis and glycosyllation of pyrimidin-2-yl 1-thio-alpha-D-manno- and -alpha-L-rhamnopyranoside.CARBOHYDRATE RESEARCH,310(2015-01-02),135-139.
MLA	Ding, XL,et al."Synthesis and glycosyllation of pyrimidin-2-yl 1-thio-alpha-D-manno- and -alpha-L-rhamnopyranoside".CARBOHYDRATE RESEARCH 310.2015-01-02(1998):135-139.