Catalytic decomposition of hydrazine on iron nitride cataltysts in microreactor; 氮化铁催化剂上肼分解研究
Zheng MY(郑明远) ; Chen XW(陈小伟) ; Cheng RH(程瑞华) ; Wang XD(王晓东) ; Li N(李宁) ; Sun J(孙军) ; Zhang T(张涛)
2004-06-02
会议名称space propulsion 2004
会议日期2004-6-2
会议地点意大利
其他题名氮化铁催化剂上肼分解研究
页码17/6
通讯作者张涛
中文摘要a series of iron nitride catalysts were prepared by temperature-programmed reaction method and evaluated in a microreactor for hydrazine decomposition. the catalytic activity of silica-supported iron nitride was apparently higher than that of silica-supported iron oxide and iron catalysts. the noble-metal-like character of the nitride may be responsible for the high catalytic activity. bulk iron nitride catalysts prepared at different temperatures had different bulk structures and different catalytic activities. the catalysts prepared at lower temperatures contained more nitrogen in the bulk and were better than those prepared at higher temperatures. iron nitride with higher surface area and smaller particle size produced higher catalytic activity and higher h2 selectivity at high temperatures. iron nitride catalyst was also compared with molybdenum nitride and niobium nitride, and the catalytic activities for hydrazine decomposition increased in the order nbn <
会议主办者欧洲航天局
学科主题物理化学
语种中文
内容类型会议论文
源URL[http://159.226.238.44/handle/321008/111660]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
推荐引用方式
GB/T 7714
Zheng MY,Chen XW,Cheng RH,et al. Catalytic decomposition of hydrazine on iron nitride cataltysts in microreactor, 氮化铁催化剂上肼分解研究[C]. 见:space propulsion 2004. 意大利. 2004-6-2.
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