| Copper/iron-cocatalyzed cascade perfluoroalkylation/cyclization of 1,6-enynes with iodoperfluoroalkanes | |
| Xia, Xiao-Feng1; Yu, Jipan2; Wang, Dawei1 | |
| 刊名 | Advanced synthesis & catalysis
 |
| 2018-02-01 | |
| 卷号 | 360期号:3页码:562-567 |
| 关键词 | Cascade cyclization 1,6-enynes Iodoper-fluoroalkanes Fluoroalkylated pyrrolidines Copper/iron-cocatalyzed |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.201701258 |
| 通讯作者 | Xia, xiao-feng(xiaxf@jiangnan.edu.cn) |
| 英文摘要 | A copper/iron-cocatalyzed fluoroalkylative cyclization of 1,6-enynes with readily available iodoperfluoroalkanes reagents for the synthesis of the corresponding fluoroalkylated pyrrolidines and benzofuran derivatives is reported. this novel protocol provides a mild method for the construction of csp(3)-cf2 and exocyclic double bonds in one step with high regio- and stereo-selectivities. |
| WOS关键词 | CARBONYL ALKYL BROMIDES ; OXIDATIVE CYCLIZATION ; RADICAL CYCLIZATION ; FUNCTIONALIZATION ; 1,N-ENYNES ; 1,7-ENYNES ; ANNULATION ; ENYNES ; CARBOCYCLIZATION ; HETEROCYCLES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Applied ; Chemistry, Organic |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000424093900026 |
| 内容类型 | 期刊论文 |
| URI标识 | http://www.corc.org.cn/handle/1471x/2177919 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Xia, Xiao-Feng |
| 作者单位 | 1.Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Synthet & Biol Colloids, Minist Educ, Wuxi 214122, Jiangsu, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Xiao-Feng,Yu, Jipan,Wang, Dawei. Copper/iron-cocatalyzed cascade perfluoroalkylation/cyclization of 1,6-enynes with iodoperfluoroalkanes[J]. Advanced synthesis & catalysis,2018,360(3):562-567. |
| APA | Xia, Xiao-Feng,Yu, Jipan,&Wang, Dawei.(2018).Copper/iron-cocatalyzed cascade perfluoroalkylation/cyclization of 1,6-enynes with iodoperfluoroalkanes.Advanced synthesis & catalysis,360(3),562-567. |
| MLA | Xia, Xiao-Feng,et al."Copper/iron-cocatalyzed cascade perfluoroalkylation/cyclization of 1,6-enynes with iodoperfluoroalkanes".Advanced synthesis & catalysis 360.3(2018):562-567. |
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