Luminescence mechanism and thermal stabilities of a white silicate phosphor for multifunctional applications | |
Sun, Qisheng1,2; Li, Xuemin1; Du, Yide1; Zhao, Bo3; Li, Hua1; Huang, Yan4; Ci, Zhipeng1,2; Zhang, Jiachi1; Ma, Ji2; Wang, Yuhua1,2 | |
刊名 | Journal of the american ceramic society |
2017 | |
卷号 | 100期号:1页码:193-203 |
关键词 | Luminescence Optical materials/properties Phosphors Thermal properties |
ISSN号 | 0002-7820 |
DOI | 10.1111/jace.14480 |
通讯作者 | Ci, zhipeng(cizhp@lzu.edu.cn) ; Zhang, jiachi(zhangjch@lzu.edu.cn) |
英文摘要 | A series of dy3+-doped sr2(1-y)ca2yy8(sio4)(6)o-2 (0 y 1) white phosphors were synthesized by the solid-state reaction. all samples crystallize into a hexagonal crystal system with space group p6(3)/m (176) by the determination of xrd rietveld refinements. with the change in ca/sr ratio, the crystal environment of active ions is lightly affected. upon excitation by uv/vuv/cathode ray sources, the samples present an efficient white light emission with significant differences in the blue/yellow ratio of dy3+ characteristic transitions. based on luminescence properties, decay times and thermal properties, the interesting phenomenon with excitation energy increasing from uv to electron beam can be reasonably explained by a potential mechanism we proposed. with the introduction of bi3+, the white emission intensity is rapidly enhanced and the optimal intensity reaches to 3.75 times compared with the single doped dy3+ sample. to evaluate the applicability of this phosphor, we packaged two light-emitting diode devices and measured the actual luminescence efficacies and cie chromaticity coordinates. these results indicate that the silicate phosphors have the potential for multifunctional application in ultraviolet-based light-emitting diodes, mercury-free lamps, and field-emission displays. |
WOS关键词 | LIGHT-EMITTING-DIODES ; FIELD-EMISSION DISPLAYS ; SOL-GEL SYNTHESIS ; CRYSTAL-STRUCTURE ; UV-LEDS ; PHOTOLUMINESCENCE ; TEMPERATURE ; GREEN ; CE3+ ; TB3+ |
WOS研究方向 | Materials Science |
WOS类目 | Materials Science, Ceramics |
语种 | 英语 |
出版者 | WILEY-BLACKWELL |
WOS记录号 | WOS:000393862800023 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2176828 |
专题 | 高能物理研究所 |
通讯作者 | Ci, Zhipeng; Zhang, Jiachi |
作者单位 | 1.Lanzhou Univ, Key Lab Special Funct Mat & Struct Design, Minist Educ, Lanzhou, Peoples R China 2.Lanzhou Univ, Key Lab Magnetism & Magnet Mat, Minist Educ, Lanzhou, Peoples R China 3.Lanzhou Univ, Sch Phys Sci & Technol, Dept Elect Mat, Lanzhou, Peoples R China 4.Chinese Acad Sci, Lab Beijing Synchrotron Radiat, Inst High Energy Phys, Beijing, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, Qisheng,Li, Xuemin,Du, Yide,et al. Luminescence mechanism and thermal stabilities of a white silicate phosphor for multifunctional applications[J]. Journal of the american ceramic society,2017,100(1):193-203. |
APA | Sun, Qisheng.,Li, Xuemin.,Du, Yide.,Zhao, Bo.,Li, Hua.,...&Wang, Yuhua.(2017).Luminescence mechanism and thermal stabilities of a white silicate phosphor for multifunctional applications.Journal of the american ceramic society,100(1),193-203. |
MLA | Sun, Qisheng,et al."Luminescence mechanism and thermal stabilities of a white silicate phosphor for multifunctional applications".Journal of the american ceramic society 100.1(2017):193-203. |
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