Serial silver clusters biomineralized by one peptide | |
Cui, Yanyan; Wang, Yaling; Liu, Ru; Sun, Zhipeng; Wei, Yueteng; Zhao, Yuliang; Gao, Xueyun | |
刊名 | Acs nano
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2011-11-01 | |
卷号 | 5期号:11页码:8684-8689 |
关键词 | Silver cluster Peptide Biomineralization Reduction potential Secondary structure |
ISSN号 | 1936-0851 |
DOI | 10.1021/nn202566n |
通讯作者 | Gao, xueyun(gaoxy@ihep.ac.cn) |
英文摘要 | The artificial peptide with amino acid sequence ccyrgrkkrrqrrr was used to biomineralize serial ag clusters. under different alkaline conditions, dusters with red and blue emission were biomineralized by the peptide, respectively. the matrix-assisted laser desorption/ionization time-of-flight mass spectra implied that the red-emitting duster sample was composed of ag(28), while the blue-emitting cluster sample was composed of ag(5), ag(6), and ag(7). the uv-visible absorption and infrared spectra revealed that the peptide phenol moiety reduced ag ions and that formed ag dusters were captured by peptide thiol moieties. the phenol reduction potential was controlled by the alkalinity and played an important role in determining the ag cluster size. circular dithroism observations suggested that the alkalinity tuned the peptide secondary structure, which may also affect the ag cluster size. |
WOS关键词 | AG NANOCLUSTER FORMATION ; QUANTUM DOTS ; BIOMIMETIC SYNTHESIS ; GOLD NANOCLUSTERS ; NANOPARTICLES ; PROTEIN ; FLUOROPHORES ; FLUORESCENCE ; BRIGHT ; CELLS |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS类目 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000297143300026 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2176113 |
专题 | 高能物理研究所 |
通讯作者 | Gao, Xueyun |
作者单位 | Chinese Acad Sci, Inst High Energy Phys, Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Cui, Yanyan,Wang, Yaling,Liu, Ru,et al. Serial silver clusters biomineralized by one peptide[J]. Acs nano,2011,5(11):8684-8689. |
APA | Cui, Yanyan.,Wang, Yaling.,Liu, Ru.,Sun, Zhipeng.,Wei, Yueteng.,...&Gao, Xueyun.(2011).Serial silver clusters biomineralized by one peptide.Acs nano,5(11),8684-8689. |
MLA | Cui, Yanyan,et al."Serial silver clusters biomineralized by one peptide".Acs nano 5.11(2011):8684-8689. |
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