Template-assisted syntheses of porous metal methylphosphonates

	Template-assisted syntheses of porous metal methylphosphonates
	Wu, ZB ; Tian, JC ; Liu, ZM ; Tian, P ; Xu, L ; Yang, Y ; Zhang, YY ; Bao, XH ; Liu, XM ; Liu, XC
刊名	journal of porous materials
	2006
卷号	13 期号:1 页码:73-80
关键词	dibutyl methylphosphonate template-assisted synthesis porous material metal methylphosphonate
通讯作者	刘中民
产权排序	1;1
英文摘要	neutral dibutyl methylphosphonate (dbmp) is used as a template to prepare porous metal methylphosphonates (metal = aluminum, titanium, zirconium). the removal of dbmp in the as-synthesized materials could be easily achieved by evaporation under vacuum without destroying the hybrid structure, as evidenced by elemental analyses, ft-ir spectra, c-13 cp/mas nmr and nitrogen adsorption-desorption isotherms. thermal analyses show that three porous hybrid samples have high thermal stability in air. the exothermic weight losses due to oxidation combustion of organic species occluded in samples appear after 730 k. furthermore, the templating effect of dbmp is also confirmed by comparing the hybrid materials synthesized in the presence or the absence of the template.
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, applied ; chemistry, physical ; materials science, multidisciplinary
研究领域[WOS]	chemistry ; materials science
关键词[WOS]	carbon molecular-sieves ; dimethyl methylphosphonate ; organic templates ; silica ; oxides ; adsorption ; design ; ir
收录类别	SCI
原文出处	true
语种	英语
WOS记录号	WOS:000235808000009
公开日期	2010-11-30
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/93681]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Nat Gas Utilizat & Appl Catalysis Lab, Dalian 116023, Peoples R China 2.Jiaozuo Univ, Dept Biochem & Environm Engn, Jiaozuo 454003, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Wu, ZB,Tian, JC,Liu, ZM,et al. Template-assisted syntheses of porous metal methylphosphonates[J]. journal of porous materials,2006,13(1):73-80.
APA	Wu, ZB.,Tian, JC.,Liu, ZM.,Tian, P.,Xu, L.,...&Liu, XC.(2006).Template-assisted syntheses of porous metal methylphosphonates.journal of porous materials,13(1),73-80.
MLA	Wu, ZB,et al."Template-assisted syntheses of porous metal methylphosphonates".journal of porous materials 13.1(2006):73-80.