High performance cocktail functional monomer for making molecule imprinting polymer

	High performance cocktail functional monomer for making molecule imprinting polymer
	Meng, ZH; Wang, JF; Zhou, LM; Wang, QH; Zhu, DQ
刊名	analytical sciences
	1999-02-01
卷号	15 期号:2 页码:141-144
关键词	molecule imprinting enantiomer separation chiral stationary phase amino acid
英文摘要	in order to make a molecule imprinting polymer (mip) with highly chiral selectivity against n-t-boc-l-trp, a new kind of "cocktail" functional monomer: acrylamide+2-vinylpyridine was investigated. the mip showed impressive chiral selectivity (alpha=3.23). with the increasing of water content in the mobile phase, ionic and hydrophobic interaction were found to be responsible for the chiral recognition process instead of the hydrogen bond. tailing and peak asymmetry problems were overcome by using linear gradient elution. physical properties such as thermal stability and pore structure for the mip were also investigated.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, analytical
研究领域[WOS]	chemistry
关键词[WOS]	chiral stationary-phase ; resolution
收录类别	SCI
原文出处	true
语种	英语
WOS记录号	WOS:000078551300006
公开日期	2010-11-30
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/86809]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem & Phys, Dalian 116012, Peoples R China
推荐引用方式 GB/T 7714	Meng, ZH,Wang, JF,Zhou, LM,et al. High performance cocktail functional monomer for making molecule imprinting polymer[J]. analytical sciences,1999,15(2):141-144.
APA	Meng, ZH,Wang, JF,Zhou, LM,Wang, QH,&Zhu, DQ.(1999).High performance cocktail functional monomer for making molecule imprinting polymer.analytical sciences,15(2),141-144.
MLA	Meng, ZH,et al."High performance cocktail functional monomer for making molecule imprinting polymer".analytical sciences 15.2(1999):141-144.